工程生物炭(Fe2o3-Bc)纳米复合材料在二元和三元水溶液中的吸附性能研究

Tobias T. Shumba, Bridgette V. Musamirapamwe
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摘要

采用热解和微波活化的方法研究了工程生物炭(Fe2O3-BC)纳米复合材料对Pb (II)、甲基橙(MO)和亮蓝(BB)的二元和三元吸附。通过批量实验研究了Fe2O3BC在二元和三元水溶液中去除MO、Pb和BB的能力。MO- pb二元溶液中MO的去除率高于三元MO溶液。与二元溶液相比,在三元溶液中吸附剂用量大、浓度高、时间长才能达到最大的去除率。Langmuir图表明,等温线可以用来描述MO染料和Pb2+的吸附研究,而Temkin等温线与结果不一致。R2值接近于1,表明所得数据符合Langmuir吸附动力学等温线模型。结果表明,Fe2O3-BC纳米复合材料具有一系列独特的均相位点,可与溶液中的MO阴离子结合。因此,利用Fe2O3-BC纳米复合材料进行小规模社区水净化是一项新颖的事业。
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Investigation on the Adsorption Properties of an Engineered Biochar (Fe2o3-Bc) Nano-Composite in Binary and Ternary Aqueous Solutions
The binary and ternary adsorptions of Pb (II), methyl orange (MO) and brilliant blue (BB) on engineered biochar (Fe2O3-BC) nano-composite using pyrolysis and microwave activation were investigated in this work. Batch experiments were conducted to investigate the capacity of Fe2O3BC to remove MO, Pb and BB in binary and ternary aqueous solutions. MO removal was higher in MO-Pb binary solution than in ternary MO solution. A large amount of adsorbent dosage, high concentration and longer time were witnessed to achieve maximum removals in ternary solutions as compared to binary solutions. The Langmuir plots indicated that the isotherm can be used to describe sorption studies of both MO dye and Pb2+, while Temkin isotherm was not in agreement with the results. The closeness of R2 value to 1 indicated that the data obtained fits Langmuir Isotherm model of monolayer adsorption kinetics. It was concluded that the Fe2O3-BC nano-composite has a series of distinct homogeneous sites available for binding the MO anions in solution. Therefore, the use of Fe2O3-BC nano-composite for small scale community water purification is a novel cause.
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