{"title":"微波辐照对乙酰二茂铁氧化的影响","authors":"Y. Okada, Ryuichi Maeda","doi":"10.4236/GSC.2021.111001","DOIUrl":null,"url":null,"abstract":"Microwave-assisted reactions are an environmentally \nfriendly approach for synthesizing organic compounds. In this study, oximation \nof acetylferrocene and acetophenone was conducted under both microwave irradiation \nand conventional heating conditions. Acetylferrocene and acetophenone were \nsubjected to oximation under the two conditions in various solvent mixtures, \nand the extent of conversion was determined by 1H nuclear magnetic \nresonance spectroscopy. Microwave irradiation was found to accelerate the rate of \noximation of both acetylferrocene and acetophenone. Acceleration of the \nreaction under microwave irradiation was attributed to the efficient absorption \nof microwaves by the ferrocene nucleus.","PeriodicalId":12770,"journal":{"name":"Green and Sustainable Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2021-02-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Effect of Microwave Irradiation on Oximation of Acetylferrocene\",\"authors\":\"Y. Okada, Ryuichi Maeda\",\"doi\":\"10.4236/GSC.2021.111001\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Microwave-assisted reactions are an environmentally \\nfriendly approach for synthesizing organic compounds. In this study, oximation \\nof acetylferrocene and acetophenone was conducted under both microwave irradiation \\nand conventional heating conditions. Acetylferrocene and acetophenone were \\nsubjected to oximation under the two conditions in various solvent mixtures, \\nand the extent of conversion was determined by 1H nuclear magnetic \\nresonance spectroscopy. Microwave irradiation was found to accelerate the rate of \\noximation of both acetylferrocene and acetophenone. Acceleration of the \\nreaction under microwave irradiation was attributed to the efficient absorption \\nof microwaves by the ferrocene nucleus.\",\"PeriodicalId\":12770,\"journal\":{\"name\":\"Green and Sustainable Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2021-02-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Green and Sustainable Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.4236/GSC.2021.111001\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Green and Sustainable Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.4236/GSC.2021.111001","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Effect of Microwave Irradiation on Oximation of Acetylferrocene
Microwave-assisted reactions are an environmentally
friendly approach for synthesizing organic compounds. In this study, oximation
of acetylferrocene and acetophenone was conducted under both microwave irradiation
and conventional heating conditions. Acetylferrocene and acetophenone were
subjected to oximation under the two conditions in various solvent mixtures,
and the extent of conversion was determined by 1H nuclear magnetic
resonance spectroscopy. Microwave irradiation was found to accelerate the rate of
oximation of both acetylferrocene and acetophenone. Acceleration of the
reaction under microwave irradiation was attributed to the efficient absorption
of microwaves by the ferrocene nucleus.
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