鸵鸟脂肪在电化学活化介质中熔融特性的研究

M. Gorbacheva, V. Tarasov, A. Sapozhnikova
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摘要

近几十年来,人们对使用具有高反应性的电活化溶液的各种技术越来越感兴趣,这些技术代表了强化生产过程的强大工具包。然而,关于在电解质中熔化过程中脂肪性质变化规律的理论知识是相当零碎的,稀缺的,而且经常是相互矛盾的。本文致力于研究利用阴极液熔融过程中影响脂肪理化性质变化和得率的主要因素,以证实其使用的可行性,并建立一条获得脂肪的工业生产线。本研究以传统方法(水溶法和实验技术)在阴极液中提取的鸵鸟脂肪为研究对象,以及脂肪提取的工艺制度。结果表明,在pH = 11、温度= 100和温度= 75°С下熔化的脂肪酸值较低,分别为0.45 mg KOH/g和0.40 mg KOH/g。相反的趋势是,ECA介质的碱度连续下降,脂肪的熔化温度升高,导致实验样品中二次氧化产物的含量增加。研究发现,由于EСA介质的高反应性,阴极电解质的温度和pH升高,脂肪相内分子间相互作用减少,从而增加了脂质分子相对于其他分子的流动性。在pH为10.5和11、温度为100°С的阴极电解液中处理脂肪原料时,脂肪粘度最低(0,42和0,4 kPa?s)。结果表明,与加热温度相反,提高阴极电解质的pH值有助于使鸵鸟脂肪的过氧化值最小化。结果表明,在75℃的阴极电解液中加工原料,脂肪得率为88,4 - 90,1%,比在水中熔化时高1.4倍。在水中软化的湿法中,与所提出的加工原料的方法相比,在75℃以上的软化温度下可以实现蛋白质结构的变性和更高程度的脂肪提取。
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Research of ostrich fat properties when melting in electrochemically activated medium
In recent decades, there has been a growing scientific interest in various kinds of technologies using electro-activated solutions with high reactivity and representing a powerful toolkit for intensification of production processes. However, theoretical knowledge about the regularities of change in fat properties during melting in an electrolyte is rather fragmentary, scarce and often contradictory. The work is devoted to the study of the main factors influencing the change in physical and chemical properties and yield of fat in the process of melting using catholyte, to substantiate the feasibility of its use and develop an industrial line for obtaining fat. The object of studies was ostrich fat obtained by traditional method – by melting in water and by experimental technology – in catholyte as well as technological regimes of fat extraction. According to the data obtained, the fat melted at pH of catholyte 11, temperature 100 and 75 °С was characterized by low values of acid number – 0,45 mg KOH/g and 0,40 mg KOH/g, respectively. The opposite trend was observed with a successive decrease in the alkalinity of the ECA medium and an increase in the melting temperature of the fat, which led to an increase in the content of secondary oxidation products in the experimental samples. It was found that due to the high reactivity of the EСA medium, the temperature and pH of the catholyte increased, the intermolecular interaction within the fat phase decreased, which increased the mobility of lipid molecules relative to each other. The lowest values of fat viscosity (0,42 and 0,4 kPa?s) were recorded when treating fatty raw materials in catholyte with pH 10.5 and 11 and temperature 100 °С. It is shown that increasing the pH of the catholyte contributes to minimizing the values of peroxide number of ostrich fat, in contrast to the heating temperature. It is established that processing of raw materials in catholyte at 75 °C resulted in the yield of fat 88,4–90,1%, which is almost 1,4 times higher than when melted in water. In the wet method of mellowing in water, denaturation of protein structures and a higher degree of fat extraction can be achieved at a mellowing temperature above 75 °C, in contrast to the proposed method of processing raw materials.
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