原子吸收分光光度法测定电视机印刷电路板中某些重金属和贵金属

S. L. Gbarakoro, J. Konne
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引用次数: 0

摘要

目的:利用原子吸收分光光度计(AAS)测定电视机印刷电路板(PCB)中某些重金属和贵金属的浓度,以便筛选出浓度较高的元素作为金属回收原料的目标来源。研究设计:本研究采用抓取抽样技术。研究区域是哈科特港Ogbunabali电脑村的一个垃圾场。研究地点和时间:本研究于2020年至2021年在尼日利亚河流州哈科特港Ogbunabali电脑村进行。方法:将附着在PCB上的金属组分进行机械分离,置于75ml凯氏定氮烧瓶中,然后用20ml硝酸(HNO3)消化。将制备好的样品过滤后,用蒸馏水配制至100ml,用原子吸收光谱法(岛津AA6300型)进行分析。结果:除Cd外,部分重金属(Fe,0.0644mg/l, Pb, 0.0732mg/l, Cu,0.0627mg/l, Ni, 0.1076mg/l, Cd, 0.0001mg/l)的浓度高于贵金属(Au, 0.0297mg/l, Pd, 0.0042mg/l, Ag, 0.0316mg/l, Li, 0.0019mg/l)。这证实了电子垃圾PCB主要由重金属和贵金属组成。结论:HNO3 +原子吸收光谱法可有效测定电子垃圾中的金属。因此,建议采取适当的回收方法,以减少这些电子废物造成的污染。
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Determination of Some Heavy and Precious Metals from Printed Circuit Board (PCB) from a Television Set by Atomic Absorption Spectrophometer
Aim: This research work aimed to determine the concentrations of some heavy and precious metals from printed circuit board (PCB) of a television set using Atomic Absorption Spectrophotometer (AAS) in order to identify elements with higher concentration as target source of raw materials for metal recovery. Study Design: Grab sampling technique was applied in this study. The study area was a refuse dumb site at computer village Ogbunabali, Port Harcourt. Place and Duration of Study: This study was carried out at computer village Ogbunabali, Port Harcourt, Rivers State, Nigeria between 2020 and 2021. Methodology: The metal fractions attached to the PCB were subjected to mechanical separation, placed inside a 75ml Kjeldahl flask and thereafter digested with a 20ml nitric acid (HNO3). The prepared sample was filtered, then made up to 100ml using distilled water and analysed using AAS (Shimadzu model AA6300). Results: The results showed the presence of some heavy metals such as: (Fe,0.0644mg/l, Pb, 0.0732mg/l, Cu,0.0627mg/l, Ni, 0.1076mg/l and Cd, 0.0001mg/l) in higher concentrations (apart from Cd) than the precious metals (Au, 0.0297mg/l, Pd, 0.0042mg/l, Ag, 0.0316mg/l and Li, 0.0019mg/l). This confirmed that the PCB which is an electronic waste was largely made up of heavy and precious metals. Conclusion: Metals can be determined effectively from electronic waste using HNO3 and AAS. It is therefore, recommended that proper recycling methods should be put in place in order to reduce the pollution caused by these electronic wastes.
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