富SrO区Bi2O3CaOSrOCuO体系相图

B.V. Slobodin, V.G. Vassiliev, E.E. Soldatova
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引用次数: 1

摘要

实验发现,系统的相图Bi2O3曹“SrO”措SrO-rich地区在850°C露天包括三个基本的四面体:“曹SrO”Sr6Bi2O11Sr2CuO3,曹Sr2CuO3Sr6Bi2O11Sr3 5 ca0 5 bi2o7 Sr3Bi2O6Sr6Bi2O11Sr3 5 ca0 5 bi2o7Sr2CuO3。在所考虑的相应氧化物浓度区间内,在上述条件下不形成季系氧化物。
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Phase diagram for the system Bi2O3CaOSrOCuO in the SrO-rich region

It has been found experimentally that phase diagram for the system Bi2O3CaOSrOCuO in SrO-rich region at 850°C in the open air includes three elementary tetrahedra: CaOSrOSr6Bi2O11Sr2CuO3, CaOSr2CuO3Sr6Bi2O11Sr3,5Ca0,5Bi2O7 and Sr3Bi2O6Sr6Bi2O11Sr3,5Ca0,5Bi2O7 Sr2CuO3. In the considered interval of corresponding oxide concentrations quaternary oxides are not formed under the above conditions.

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