不同链长芳基硫醇与氧化镉纳米颗粒的DNA/RNA聚合研究

A. Heidari
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引用次数: 1

摘要

纳米CdO在紫外可见区有很强的等离子体吸收峰。CdO纳米颗粒表面与芳基硫醇化合物之间存在很强的相互作用。芳基硫醇类化合物引起与DNA/RNA连接的CdO纳米颗粒聚集,从而导致CdO纳米颗粒表面等离子体激元在550 (nm)处变宽,并在更高波长处出现新峰。本项目利用纳米CdO的光学特性,对不同芳基硫醇与纳米CdO之间的相互作用进行了时间研究。结果表明,链长较短的芳基硫醇类化合物与CdO纳米颗粒的相互作用更快。因此,提出了一种利用表面等离子体吸收红移快速鉴别不同链长的芳基硫醇的方法。
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Study of DNA/RNA Aggregation Linked to Cadmium Oxide (CdO) Nanoparticles by Aryl Mercaptanes with Various Chain Length
CdO nanoparticles show a strong peak of Plasmon absorption in ultraviolet-visible zone. A strong interaction exists between the surface of CdO nanoparticles and aryl mercaptan compounds. Aryl mercaptan compounds cause to aggregation of CdO nanoparticles linked to DNA/RNA and hence, lead to widening of peak Plasmon of CdO nanoparticles surface at 550 (nm) and emerging a new peak at higher wavelength. In the current project, this optical characteristic of CdO nanoparticles is used to time investigate of interaction between different aryl mercaptanes and CdO nanoparticles. The results were shown that aryl mercaptan compounds with shorter chain length interact faster with CdO nanoparticles. Therefore, a simple and fast method for identification of aryl mercaptanes with various chain length using red shift in surficial Plasmon absorption is presented.
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