同步辐射对铝合金粉钙钡氧化的原位研究

V. Shevchenko, D. Eselevich, A. Ancharov, B. Tolochko
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引用次数: 0

摘要

研究了0.88 at和0.26 at的钙钡氧化铝合金初始粉末和氧化产物的相组成和结构。采用同步辐射在1273 K的空气中以10 K/min的速率程控加热,首次用衍射法对各%的掺杂剂进行了研究。结果表明,由于氧化产物相组成的不均匀性和颗粒表面氧化壳的结构变化,氧化铝失去了其高保护性能,激活了金属氧化。
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In Situ Investigation of Oxidation of Aluminum Alloy Powders with Calcium and Barium by Synchrotron Radiation
The phase composition and structure of initial powders and the products of oxidation of aluminum alloys with calcium and barium containing 0.88 and 0.26 at.% of dopants, respectively, have been studied for the first time by the diffraction method with the use of synchrotron radiation during programmed heating in air up to 1273 K at a rate of 10 K/min. It was established that as a result of the heterogeneity of the phase composition of the oxidation products and the structural changes in the oxide shell on the particle surface, aluminum oxide loses its high protective properties and metal oxidation is activated.
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