{"title":"间膜和间膜酮与偶氮二羧酸二乙酯的反应","authors":"P. Jeffs, H. F. Campbell, R. Hawks","doi":"10.1039/C2971001338B","DOIUrl":null,"url":null,"abstract":"The alkaloids mesembrine (1; R1= R2= O) and mesembrenone (2) undergo a novel oxidation with diethyl azodicarboxylate to afford the β-enaminoketones (4) and (6), respectively.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"37 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"8","resultStr":"{\"title\":\"The reaction of mesembrine and mesembrenone with diethyl azodicarboxylate\",\"authors\":\"P. Jeffs, H. F. Campbell, R. Hawks\",\"doi\":\"10.1039/C2971001338B\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The alkaloids mesembrine (1; R1= R2= O) and mesembrenone (2) undergo a novel oxidation with diethyl azodicarboxylate to afford the β-enaminoketones (4) and (6), respectively.\",\"PeriodicalId\":17278,\"journal\":{\"name\":\"Journal of The Chemical Society D: Chemical Communications\",\"volume\":\"37 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"8\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society D: Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C2971001338B\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society D: Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C2971001338B","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The reaction of mesembrine and mesembrenone with diethyl azodicarboxylate
The alkaloids mesembrine (1; R1= R2= O) and mesembrenone (2) undergo a novel oxidation with diethyl azodicarboxylate to afford the β-enaminoketones (4) and (6), respectively.