功能化石墨烯纳米板填充的高性能聚酰胺1010/聚氨酯共混物:物理性能与技术应用

Ayesha Kausar
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引用次数: 10

摘要

摘要本实验制备了新型聚氨酯(PU),并与聚酰胺1010 (PA1010)共混。基于形貌、分子量、多分散性指数、热应力和剪切性能,选择PA1010/PU(80:20)共混物作为增强石墨烯纳米板(GNP)的基体材料。采用不同的GNP (1-5 wt.%)负载制备了PA1010/PU/GNP纳米复合材料。扫描电镜(SEM)显示,当PU质量分数为5%时,PA1010/PU共混物的相容性较好。由于纳米填料与基体之间的物理相互作用,包含功能性GNP导致斑点形态的形成。在PA1010/PU/GNP 3纳米复合材料中,T0(532℃)远高于未填充共混物(389℃)。同样,其他热性能(T10 565℃;PA1010/PU/GNP纳米复合材料的Tmax(599℃)显著高于共混物和纳米复合材料。极限氧指数测定表明,PA1010/PU/GNP 1-3纳米复合材料系列的不可燃性较好(50% ~ 57%)。
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Exploration on high performance polyamide 1010/polyurethane blends filled with functional graphene nanoplatelet: physical properties and technical application
ABSTRACTIn this attempt, novel polyurethane (PU) was prepared and blended with polyamide 1010 (PA1010). Based on morphology, molecular weight, polydispersity index, thermal, and shear stress behavior, PA1010/PU (80:20) blend was opted as matrix material for graphene nanoplatelet (GNP) reinforcement. PA1010/PU/GNP nanocomposites were prepared using various GNP loadings (1–5 wt.%). According to scanning electron microscopy (SEM), PA1010/PU blend with 5 wt.% PU revealed better compatibility. Inclusion of functional GNP resulted in formation of speckled morphology due to physical interaction between nanofiller and the matrix. In the case of PA1010/PU/GNP 3 nanocomposite, T0 (532 oC) was much higher than the unfilled blend (389 oC). Similarly, other thermal properties (T10 565 oC; Tmax 599 oC) of PA1010/PU/GNP 3 nanocomposite were significantly higher than the blends and nanocomposites. Limiting oxygen index measurement indicated better non-flammability of PA1010/PU/GNP 1–3 nanocomposite series (50%–57%) relat...
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