{"title":"研究低温晶体生长对无铅BCT-BZT陶瓷结构和铁电性能的影响","authors":"S. Thakur, Mamta Shandilya, M. Graça, M. Valente","doi":"10.1080/07315171.2020.1810985","DOIUrl":null,"url":null,"abstract":"Abstract Barium Zirconate Titanate-Barium Calcium Titanate (BCT-BZT) is one of the lead-free systems, which exhibits remarkable ferroelectric properties akin to lead-based perovskite materials. In this study, we have synthesized x(Ba0.85Ca0.15)TiO3-(1−x)Ba(Zr0.15Ti0.85)O3 (where x = 0.4, 0.5, 0.6) monophonic powders by hydrothermal method at 150 °C. X-ray diffraction reveals the pure tetragonal phase. Scanning electron microscopy (SEM) studies make known that the crystal growth is uniform due to low temperature, and that the ceramics are highly dense and polycrystalline. The single semicircle indicates bulk behavior. The bulk resistance decreases with the increase in temperature showing a typical semiconducting property, negative temperature coefficient of resistance (NTCR) behavior.","PeriodicalId":50451,"journal":{"name":"Ferroelectrics Letters Section","volume":"21 1","pages":"76 - 89"},"PeriodicalIF":1.3000,"publicationDate":"2020-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"6","resultStr":"{\"title\":\"To study the effect of low temperature crystal growth on the structural and ferroelectric properties of lead-free BCT-BZT ceramic\",\"authors\":\"S. Thakur, Mamta Shandilya, M. Graça, M. Valente\",\"doi\":\"10.1080/07315171.2020.1810985\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract Barium Zirconate Titanate-Barium Calcium Titanate (BCT-BZT) is one of the lead-free systems, which exhibits remarkable ferroelectric properties akin to lead-based perovskite materials. In this study, we have synthesized x(Ba0.85Ca0.15)TiO3-(1−x)Ba(Zr0.15Ti0.85)O3 (where x = 0.4, 0.5, 0.6) monophonic powders by hydrothermal method at 150 °C. X-ray diffraction reveals the pure tetragonal phase. Scanning electron microscopy (SEM) studies make known that the crystal growth is uniform due to low temperature, and that the ceramics are highly dense and polycrystalline. The single semicircle indicates bulk behavior. The bulk resistance decreases with the increase in temperature showing a typical semiconducting property, negative temperature coefficient of resistance (NTCR) behavior.\",\"PeriodicalId\":50451,\"journal\":{\"name\":\"Ferroelectrics Letters Section\",\"volume\":\"21 1\",\"pages\":\"76 - 89\"},\"PeriodicalIF\":1.3000,\"publicationDate\":\"2020-03-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"6\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Ferroelectrics Letters Section\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://doi.org/10.1080/07315171.2020.1810985\",\"RegionNum\":4,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"PHYSICS, CONDENSED MATTER\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ferroelectrics Letters Section","FirstCategoryId":"101","ListUrlMain":"https://doi.org/10.1080/07315171.2020.1810985","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"PHYSICS, CONDENSED MATTER","Score":null,"Total":0}
To study the effect of low temperature crystal growth on the structural and ferroelectric properties of lead-free BCT-BZT ceramic
Abstract Barium Zirconate Titanate-Barium Calcium Titanate (BCT-BZT) is one of the lead-free systems, which exhibits remarkable ferroelectric properties akin to lead-based perovskite materials. In this study, we have synthesized x(Ba0.85Ca0.15)TiO3-(1−x)Ba(Zr0.15Ti0.85)O3 (where x = 0.4, 0.5, 0.6) monophonic powders by hydrothermal method at 150 °C. X-ray diffraction reveals the pure tetragonal phase. Scanning electron microscopy (SEM) studies make known that the crystal growth is uniform due to low temperature, and that the ceramics are highly dense and polycrystalline. The single semicircle indicates bulk behavior. The bulk resistance decreases with the increase in temperature showing a typical semiconducting property, negative temperature coefficient of resistance (NTCR) behavior.
期刊介绍：
Ferroelectrics Letters is a separately published section of the international journal Ferroelectrics. Both sections publish theoretical, experimental and applied papers on ferroelectrics and related materials, including ferroelastics, ferroelectric ferromagnetics, electrooptics, piezoelectrics, pyroelectrics, nonlinear dielectrics, polymers and liquid crystals.
Ferroelectrics Letters permits the rapid publication of important, quality, short original papers on the theory, synthesis, properties and applications of ferroelectrics and related materials.
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