表面织构对含盐含水层水环境中高合金不锈钢腐蚀疲劳行为的影响

A. Pfennig, M. Wolf, A. Kranzmann
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引用次数: 4

摘要

采用高合金马氏体不锈钢X46Cr13(1.4043)和双相不锈钢x2crnimon2232(1.4462)的不同表面(加工后的工艺表面和抛光后的表面),在德国北部盆地地热盐水中,在98℃下175 ~ 325 MPa的载荷幅值下进行了腐蚀疲劳试样的比较。表面腐蚀层和蚀坑以FeCO 3和FeOOH等碳酸盐腐蚀产物为主要析出相,与原始表面粗糙度无关。在275 MPa以上的高应力幅值下,技术表面(σa 300 MPa=5 × 10 5时的P50%)比抛光表面(σa 300 MPa=1.5 × 10 5时的P50%)的失效循环次数更多。在给定应力幅σa下,技术面k = 19.006的斜率系数大于抛光面k =8.78的斜率系数。
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The Role of Surface Texture on the Corrosion Fatigue Behavior of High Alloyed Stainless Steel Exposed to Saline Aquifer Water Environment
Corrosion fatigue specimen with different surfaces (technical surfaces after machining and polished surfaces) of high alloyed martensitic stainless steel X46Cr13 (1.4043) and duplex stai nless steel X2CrNiMoN22 3 2 (1.4462) were compared at load amplitudes from 175 MPa to 325 MPa in the geothermal brine of the N orthern German Basin at 98 °C. Surface corrosion layers and pits reveal carbonate corrosion products on the surface such as FeCO 3 and FeOOH as the main precipitation phases with no dependence on the original surface roughness . At high stress amplitudes above 275 MPa technical surfaces (P50% at σa 300 MPa=5 × 10 5 ) resulted in more cycles to failure than polished (P50% at σa 300 MPa=1.5 × 10 5 ). The greater slope coefficient for technical surfaces k = 19.006 compared to polished surfaces k =8.78 demonstrate s earlier failure at given stress amplitude σa .
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