评估低吨位化学工业的资源节约技术是否符合现有最佳技术原则

N. A. Kostikova, E. Glukhan, P. V. Kazakov, M. Antonova, D. Klimov
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摘要

目标。根据最佳可得技术原则制定定量评价新技术的方法。评价已开发的四甲基硫脲二硫化、n -环己基-2-苯并噻唑基磺酰胺、二异丙基黄原二硫化和n -苯基-2-萘胺的低吨位化工生产技术是否符合BAT原则,并与替代(已实施的、已知的)技术进行环境影响比较。采用了一种符合BAT原则的有机物质生产新技术定量评价方法。基于技术和环境指标与替代技术的综合比较指标的计算,根据BAT原则制定的新技术定量评估方法使我们能够确定生产四甲基硫脲二硫化、n -环己基-2-苯并噻唑基磺酰胺、二异丙基黄原二硫化、和n -苯基-2-萘胺,包括通过开发节约资源和减少废物的特殊技术解决方案,最大限度地减少对环境的影响,并对所取得的环境成果进行定量评估。可以确定的是,与苏联以前实施的替代技术相比,考虑的低吨位化学品生产新技术符合BAT原则,并且更环保。本文首次提出了一种根据BAT原则对新技术进行量化的方法。在对实施的生产方法作出基本技术决策阶段,为了确保符合环境安全领域技术的立法要求,以实现环境保护目标,在生产四甲基硫脲二硫化物、n -环己基-2-苯并噻唑基磺酰胺、二异丙基黄原二硫化物的低吨位技术的例子中显示了其使用的可能性。和在GosNIIOKhT中产生的n -苯基-2-萘胺。
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Assessment of resource-saving technologies in low-tonnage chemical industries for compliance with best available technologies principles
Objectives. To develop a methodology for the quantitative assessment of new technologies in accordance with the principles of best available technologies (BAT). To evaluate the developed technologies of low-tonnage chemical production of tetramethylthiuram disulfide, N-cyclohexyl-2- benzothiazolylsulfenamide, diisopropyl xanthohen disulfide, and N-phenyl-2-naphthylamine for compliance with BAT principles and compare with alternative (implemented, known) technologies in terms of environmental impact.Methods. A methodology for the quantitative assessment of new technologies for the production of organic substances in accordance with BAT principles was used.Results. The developed methodology for the quantitative assessment of new technologies in accordance with BAT principles based on the calculation of comprehensive comparison indicators with alternative technologies for technological and environmental indicators allowed us to determine the level of implemented technologies for the production of tetramethylthiuram disulfide, N-cyclohexyl-2-benzothiazolylsulfenamide, diisopropyl xanthohen disulfide, and N-phenyl-2- naphthylamine to minimize the impact on the environmental, including through the development of special technological solutions for resource conservation and waste reduction, and to conduct a quantitative assessment of the achieved environmental outcome. It is established that the considered new technologies of low-tonnage chemical production comply with BAT principles and are more environmentally advanced compared to alternative ones previously implemented in the USSR.Conclusions. For the first time, a methodology for quantifying new technologies in accordance with BAT principles is proposed. The possibility of its use at the stage of making basic technological decisions on the implemented production method in order to ensure compliance with legislative requirements for technologies in the field of environmental safety to achieve environmental protection goals is shown on the example of low-tonnage technologies for the production of tetramethylthiuram disulfide, N-cyclohexyl-2-benzothiazolylsulfenamide, diisopropyl xanthohen disulfide, and N-phenyl-2-naphthylamine created in GosNIIOKhT.
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