铂掺杂氧化锌对氢传感响应的改进

RAN Pub Date : 2016-04-01 DOI:10.11159/ICNEI16.105
Anita Hastir, N. Kohli, Ravinder Singh
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引用次数: 2

摘要

本文讨论了铂(Pt)作为掺杂剂对ZnO结构、形貌和气敏性能的影响。采用简便、经济的共沉淀法合成了氧化锌和掺杂氧化锌纳米颗粒。XRD分析表明,纯纳米结构和掺杂纳米结构均可形成六方纤锌矿结构,拉曼光谱进一步支持了这一结论。拉曼和x射线光电子能谱(XPS)研究也揭示了掺杂样品中存在缺陷。用场发射扫描电子显微镜(FESEM)研究了合成样品的形貌。为了获得气敏特性,将合成的颗粒作为厚膜涂在氧化铝衬底上,并在不同的操作温度下对氢气进行了测试。在所有样品中,0.05% Pt掺杂ZnO对氢的传感性能增强。传感响应的增加归因于掺杂样品中缺陷的存在和铂的催化性质。
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Improvement in Hydrogen Sensing Response of Zinc Oxide Doped with Platinum
In this work, the effect of Platinum (Pt) as dopant on the structural, morphological and gas sensing properties of ZnO has been discussed. ZnO and Ptdoped ZnO nanoparticles were synthesized by facile and cost effective co-precipitation technique. XRD analysis revealed the formation of hexagonal wurtzite structure for pure and doped nanostructures which was further supported by Raman studies.Raman and X-Ray photoelectron spectroscopy (XPS) investigations also reveal the presence of defects in doped samples. The morphology of the synthesised samples has been studied by field emission scanning electron microscopy (FESEM). For gas sensing characteristics the synthesized particles were applied as thick film onto an alumina substrate and tested at different operating temperatures for hydrogen gas. Among all samples, 0.05% Pt doped ZnO exhibited enhanced sensing performance towardshydrogen. The increase in sensing response is attributed to presence of defects in doped sample and the catalytic nature of platinum.
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