{"title":"三维微孔磷酸铁:[H3N(CH2)4NH3]3[Fe8(HPO4)12(PO4)2(H2O)6]的水热合成与结构测定","authors":"M.B. Korzenski, G.L. Schimek, J.W. Kolis","doi":"10.1016/S0992-4361(98)80193-8","DOIUrl":null,"url":null,"abstract":"<div><p>A new microporous iron (III) phosphate, [H<sub>3</sub>N(CH<sub>2</sub>)<sub>4</sub>NH<sub>3</sub>]<sub>3</sub>[Fe<sub>8</sub>(HPO<sub>4</sub>)<sub>12</sub>(PO<sub>4</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>6</sub>], has been prepared using low temperature hydrothermal methods and characterized by single-crystal X-ray diffraction, EDAX, infrared spectroscopy, thermogravimetric analysis and bond valence sums. The title compound crystallizes as light pink hexagonal-shaped tabs in the centrosymmetric hexagonal space group 3¯ (No.147) with <em>a</em> = <em>b</em> = 13.495(2) Å, <em>c</em> = 9.396(2) Å, V = 1481.9(4) Å<sup>3</sup> and Z = 4 with R/R<sub>w</sub> = 0.044/0.048. The compound exhibits a complicated three-dimensional microporous structure with quaternary ammonium ions acting as a template for the framework. It is similar to previously reported [HN(CH<sub>2</sub>CH<sub>2</sub>)<sub>3</sub>NH]<sub>3</sub>[Fe<sub>8</sub>(HPO<sub>4</sub>)<sub>12</sub>(PO<sub>4</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>6</sub>].</p></div>","PeriodicalId":100507,"journal":{"name":"European Journal of Solid State and Inorganic Chemistry","volume":"35 2","pages":"Pages 143-160"},"PeriodicalIF":0.0000,"publicationDate":"1998-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0992-4361(98)80193-8","citationCount":"6","resultStr":"{\"title\":\"Hydrothermal synthesis and structural determination of a three-dimensional microporous iron(III)phosphate: [H3N(CH2)4NH3]3[Fe8(HPO4)12(PO4)2(H2O)6]\",\"authors\":\"M.B. Korzenski, G.L. Schimek, J.W. Kolis\",\"doi\":\"10.1016/S0992-4361(98)80193-8\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A new microporous iron (III) phosphate, [H<sub>3</sub>N(CH<sub>2</sub>)<sub>4</sub>NH<sub>3</sub>]<sub>3</sub>[Fe<sub>8</sub>(HPO<sub>4</sub>)<sub>12</sub>(PO<sub>4</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>6</sub>], has been prepared using low temperature hydrothermal methods and characterized by single-crystal X-ray diffraction, EDAX, infrared spectroscopy, thermogravimetric analysis and bond valence sums. The title compound crystallizes as light pink hexagonal-shaped tabs in the centrosymmetric hexagonal space group 3¯ (No.147) with <em>a</em> = <em>b</em> = 13.495(2) Å, <em>c</em> = 9.396(2) Å, V = 1481.9(4) Å<sup>3</sup> and Z = 4 with R/R<sub>w</sub> = 0.044/0.048. The compound exhibits a complicated three-dimensional microporous structure with quaternary ammonium ions acting as a template for the framework. It is similar to previously reported [HN(CH<sub>2</sub>CH<sub>2</sub>)<sub>3</sub>NH]<sub>3</sub>[Fe<sub>8</sub>(HPO<sub>4</sub>)<sub>12</sub>(PO<sub>4</sub>)<sub>2</sub>(H<sub>2</sub>O)<sub>6</sub>].</p></div>\",\"PeriodicalId\":100507,\"journal\":{\"name\":\"European Journal of Solid State and Inorganic Chemistry\",\"volume\":\"35 2\",\"pages\":\"Pages 143-160\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1998-02-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S0992-4361(98)80193-8\",\"citationCount\":\"6\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"European Journal of Solid State and Inorganic Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0992436198801938\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"European Journal of Solid State and Inorganic Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0992436198801938","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 6
摘要
采用低温水热法制备了新型微孔磷酸铁(III) [H3N(CH2)4NH3]3[Fe8(HPO4)12(PO4)2(H2O)6]，并用单晶x射线衍射、EDAX、红外光谱、热重分析和键价和对其进行了表征。标题化合物在中心对称的六角形空间群3¯(No.147)中结晶为浅粉色的六角形标签，a = b = 13.495(2) Å， c = 9.396(2) Å， V = 1481.9(4) Å3, Z = 4, R/Rw = 0.044/0.048。该化合物具有复杂的三维微孔结构，季铵离子作为骨架模板。它类似于先前报道的[HN(CH2CH2)3NH]3[Fe8(HPO4)12(PO4)2(H2O)6]。
Hydrothermal synthesis and structural determination of a three-dimensional microporous iron(III)phosphate: [H3N(CH2)4NH3]3[Fe8(HPO4)12(PO4)2(H2O)6]
A new microporous iron (III) phosphate, [H3N(CH2)4NH3]3[Fe8(HPO4)12(PO4)2(H2O)6], has been prepared using low temperature hydrothermal methods and characterized by single-crystal X-ray diffraction, EDAX, infrared spectroscopy, thermogravimetric analysis and bond valence sums. The title compound crystallizes as light pink hexagonal-shaped tabs in the centrosymmetric hexagonal space group 3¯ (No.147) with a = b = 13.495(2) Å, c = 9.396(2) Å, V = 1481.9(4) Å3 and Z = 4 with R/Rw = 0.044/0.048. The compound exhibits a complicated three-dimensional microporous structure with quaternary ammonium ions acting as a template for the framework. It is similar to previously reported [HN(CH2CH2)3NH]3[Fe8(HPO4)12(PO4)2(H2O)6].
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