功能钙钛矿:结构-性能相关性

Achintya Bera, S. Yusuf
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引用次数: 0

摘要

通式为ABX3的钙钛矿结构在晶体结构与电子、磁性、光学和催化性能的相关性方面显示出其多维性。钙钛矿由于其巨大的通用性而被广泛应用。在本章中,介绍了具有几种功能性质的氧化物钙钛矿化合物ABO3的结构-性能相关性。特别是,中子和x射线衍射结果揭示了几个重要的物理性质,如磁性、多铁性、电子(CMR)和SOFC电极与晶体结构的直接关系。
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Functional Perovskites: Structure-Properties Correlations
The perovskite structure with general formula ABX3 shows its multidimensional nature in regards to correlations of crystal structures with electronic, magnetic, optical, and catalytic properties. Perovskites are utilized in a large range of applications due to their tremendous versatility. In this chapter, structure-properties correlations in oxide perovskite compounds ABO3 having several functional properties are presented. In particular, neutron and x-ray diffraction results are described to reveal a direct correlation of several important physical properties, such as magnetic, multiferroic, electronic (CMR), and SOFC electrodes with the crystal structures.
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