水诱导溶菌酶的生物驻极体状态

M. G. Bridelli, R. Capelletti, G. Ruani, A. Vecli
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引用次数: 2

摘要

通过耦合TSDC和ir吸收测量,研究了不同水合水平下水在溶菌酶等生物驻极体中的作用。除了Mascarenhas报道的312 k波段外,我们的TSDC光谱还显示了与不同配位的水相关的较弱的新波段。在固定起始水化水平下,采用动态真空等温时效方法研究了试样含水量随时间的变化规律:1)TSDC谱谱整体减小,且高温侧减小更为明显;2)与水相关的ir谱带减小。
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Water induced bioelectret state in lysozyme
The role of water in a bioelectret such as lysozyme at different hydration levels is studied by coupling TSDC and i.r. absorption measurements. In addition to the 312 K-band reported by Mascarenhas, our TSDC spectra exhibit new, weaker but anyway relevant bands related to water in different coordinations. At fixed starting hydration levels, the time evolution of water contents was studied by isothermal sample aging in dynamic vacuum: 1) the whole TSDC spectrum was reduced, the decrease being more relevant on the high temperature side and 2) the water related i.r. bands decreased as well.
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