水热炭化辅助酸活化法制备水葫芦纳米多孔碳

Nattaya Suksai, Sirayu Chanpee, N. Kaewtrakulchai, S. Chutipaijit, M. Fuji, A. Eiad-ua
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摘要

水葫芦(WHs),这是泰国农业的重要废物。它由半纤维素、纤维素和木质素组成,具有生产碳材料的潜力。本研究以水葫芦为原料,研究了水热温度200℃、反应时间(4 ~ 24 h)以及H3PO4活化对其孔隙度和比表面积的影响,通过水热炭化法制备了水葫芦炭材料。通过扫描电子显微镜(SEM)、傅里叶变换红外光谱(FT-IR)、x射线衍射(XRD)对样品的化学物理性质进行了表征。结果表明,水葫芦纳米孔碳材料的含碳量随HTC温度和时间的增加而增加。采用H3PO4活化催化剂,在200℃下还原12 h,炭表面孔隙度增加是合成吸附剂前驱体材料的最佳条件。
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Synthesis of Nanoporous Carbon from Water Hyacinth via Hydrothermal Carbonization Process Assisted Acid Activation
Water hyacinth (WHs), which is a crucial waste material from agriculture in Thailand. It consists of hemicellulose, cellulose and lignin that has a potential for carbon material production. In this research, carbon material was prepared from Water hyacinth via hydrothermal Carbonization (HTC) by study the effect of hydrothermal temperature 200 °C, reaction time (4-24 h) and using H3PO4 activation to develop porosity and surface area. The sample have been characterized chemical-physical properties of carbon nanoporous materials through a scanning electron microscope (SEM), fourier transformer Infrared spectroscopy (FT-IR), X-ray diffraction (XRD). The results revealed that carbon content of nanoporous carbon materials from water hyacinth were increased with higher HTC temperature and time. Performing HTC at 200 °C for 12 h and using H3PO4 activation catalyst shows porosity increased on char surface is the optimum condition to synthesis of precursor materials for good adsorbent.
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