布洛芬-锡配合物的形态、光化学和光谱研究

A. al-ani, D. Ahmed, M. Al-Mashhadani, Mustafa Abdallh, E. Yousif
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引用次数: 0

摘要

制备了聚氯乙烯(PVC)薄膜,并用紫外光研究了聚氯乙烯薄膜的光稳定性。通过计算PVC降解速率常数,评价了本研究合成的布洛芬-锡聚合物配合物作为光稳定剂辐照300小时后的效率。研究结果表明,与空白PVC相比,添加剂(布洛芬-锡配合物)对PVC降解常数的降低有显著影响,未添加添加剂的PVC降解常数速率大于添加添加剂时的降解常数速率。利用场发射扫描电镜(FESEM)研究了添加添加剂后辐照聚合物膜的表面形貌。可以看出,添加了添加剂的聚合物膜的粗糙度比辐照过的PVC(空白)要小。在本研究中,有机锡配合物作为光稳定剂,通过吸收入射光,并随着时间的推移将其转化为聚合物链的热量,从而保持PVC不被分解。
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Morphological, Photochemical and Spectroscopic Studies of Ibuprofen-Tin Complexes
Poly(vinyl chloride) (PVC) was prepared and the photo-stabilization of polymer films was studied using ultraviolet (UV) light. The efficiency of the synthesized polymer complex of ibuprofen-tin which is the photo-stabilizer in this study afterward of 300 hours of irradiation were evaluated by calculate the constant of PVC degradation rate. The outcome of this research has shown that the additives (ibuprofen-tin complexes) effect significantly on the decreased degradation constant compare to blank PVC, without additives the rate of degradation constant of PVC is greater than when the additives are added. The surface morphologies of the irradiated polymer film with additives were researches utilizing Field Emission Scanning Electron Microscope (FESEM). It can be seen that the polymer film with added additives is less roughness than the irradiated PVC (blank). The organotin complexes behave in this study as a photostabilizer to maintain the PVC from any decomposition by absorbing the incident light and convert it over the time as a heat to the polymeric chain.
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