E. D. Finashina, A. Kucherov, L. Kustov, Haiyong Cai, A. Krzywicki
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Effect of feedstock impurities on activity and selectivity of V-Mo-Nb-Te-Ox catalyst in ethane oxidative dehydrogenation
Abstract The effect of CH4, C2H4, CO2, CH3OH, and (CH3S)2 on activity and selectivity of V-Mo-Nb-Te-Ox catalyst for ethane oxidative dehydrogenation is studied. Methane acts as a chemically inert diluent of the gas mixture. Presence of ethylene in feed stream does not have significant effect on the rate of ethane dehydrogenation but causes slight drop in ethylene selectivity. CO2 added is not involved in chemical transformations but suppress slightly ethane conversion and selectivity. Contamination of the gas stream with small amounts of either methanol or dimethyldisulfide (DMDS) does not reduce either activity or selectivity of the catalyst in ethane oxidative dehydrogenation.
期刊介绍：
The Journal of advanced oxidation technologies (AOTs) has been providing an international forum that accepts papers describing basic research and practical applications of these technologies. The Journal has been publishing articles in the form of critical reviews and research papers focused on the science and engineering of AOTs for water, air and soil treatment. Due to the enormous progress in the applications of various chemical and bio-oxidation and reduction processes, the scope of the Journal is now expanded to include submission in these areas so that high quality submission from industry would also be considered for publication. Specifically, the Journal is soliciting submission in the following areas (alphabetical order): -Advanced Oxidation Nanotechnologies -Bio-Oxidation and Reduction Processes -Catalytic Oxidation -Chemical Oxidation and Reduction Processes -Electrochemical Oxidation -Electrohydraulic Discharge, Cavitation & Sonolysis -Electron Beam & Gamma Irradiation -New Photocatalytic Materials and processes -Non-Thermal Plasma -Ozone-based AOTs -Photochemical Degradation Processes -Sub- and Supercritical Water Oxidation -TiO2 Photocatalytic Redox Processes -UV- and Solar Light-based AOTs -Water-Energy (and Food) Nexus of AOTs
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