纳米方法面临巨大挑战:纳米硅基堵水密封系统

Ayman Almohsin, Jin-Chao Hung, M. Alabdrabalnabi, M. Sherief
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引用次数: 2

摘要

在石油工业中,最大限度地减少油井产生的不必要的水是非常必要的。这将通过采用新的创新技术来提高成熟井的经济寿命。纳米硅基密封液的开发是为了解决与不希望产生的水相关的问题。这项工作的目的是在广泛的参数范围内评估一种基于纳米二氧化硅的新开发的新型堵水系统。这种改性的纳米二氧化硅具有光滑的球形,并且存在于狭窄的粒径分布中。因此,它可以用于不同产水机制的水管理,包括高渗透条纹、虫孔和裂缝性油藏。为了对新型纳米二氧化硅/活化剂进行系统评价,需要在给定的油藏条件下,对凝胶化之前、过程中和之后的化学性质进行检查。这些特性包括溶液初始粘度、凝胶时间、注入性以及在不同驱油体系中形成的凝胶抵抗外力作用的强度。本文详细介绍了一种有前途的方法来控制不希望的水产量使用环保,成本效益的纳米二氧化硅。实验结果表明,纳米二氧化硅最初表现出低粘度,因此在混合和泵送要求方面具有显著的优势。纳米二氧化硅凝胶化时间是注入化学处理的关键因素,可以通过调整活化剂浓度来适应所需温度下的现场要求。此外,在碳酸盐岩心塞、Berea砂岩和人工压裂(金属管)中进行了岩心注水试验,以研究化学处理的性能。流动测试清楚地表明,在所有测试类型的岩石中,产水量都显著下降。环境扫描电镜(SEM)结果表明,纳米二氧化硅产品填充了多孔介质;因此,它堵塞了整个岩心塞。一种使用纳米技术封堵近井区域的新型高效密封胶已经开发出来。本文将介绍其性能和控制其在多孔介质中传播速率的方法。基于这些结果,必须强调的是,这些微小颗粒在油藏堵水方面具有很好的应用前景。
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A Nano Method for a Big Challenge: Nanosilica-Based Sealing System for Water Shutoff
Minimizing unwanted water production from oil wells is highly required in the petroleum industry. This would lead to improved economic life of mature wells that involve new and innovative technologies. Nanosilica-based sealing fluid has been developed to address problems associated with unwanted water production. The objective of this work is to evaluate a newly developed novel water shutoff system based on nanosilica over a wide range of parameters. This modified nanosilica has a smooth, spherical shape, and are present in a narrow particle size distribution. Therefore, it can be used for water management in different water production mechanisms including high permeability streak, wormhole, and fractured reservoirs. A systematic evaluation of novel nanosilica/activator for water shutoff purposes requires the examination of the chemical properties before, during, and after gelation at given reservoir conditions. These properties are solution initial viscosity, gelation time, injectivity, and strength of the formed gel against applied external forces in different flooding systems. This paper details a promising method to control undesired water production using eco-friendly, cost-effective nanosilica. Experimental results revealed that nanosilica initially exhibited a low viscosity and hence providing a significant advantage in terms of mixing and pumping requirements. Nanosilica gelation time, which is a critical factor in placement of injected-chemical treatment, can be tailored by adjusting the activator concentration to match field requirements at the desired temperature. In addition, core flood tests were conducted in carbonate core plugs, Berea sandstone rock, and artificially fractured (metal tube) to investigate the performance of the chemical treatment. Flow tests clearly indicated that the water production significantly dropped in all tested types of rocks. The environmental scanning electron microscope (SEM) results showed the presence of SiO-rich compounds suggesting that the tested nanosilica product filled the porous media; therefore, it blocked the whole core plug. A novel cost-effective sealant that uses nanotechnology to block the near wellbore region has been developed. The performance and methods controlling its propagation rate into a porous medium will be presented. Based on the outcomes, it must be emphasized that these trivial particles have a promising application in the oil reservoir for water shutoff purposes.
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