不同环境条件对管道腐蚀速率影响的实验研究

O. Adeyanju, L. Oyekunle
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摘要

据估计,尼日利亚工业每年在腐蚀方面的支出约为1850万美元,由于石油和天然气行业设施和运营条件的特殊性,其成本占该成本的65%以上。尽管在石油和天然气工业中使用了镀锌管道,并在原油管道和其他金属结构上应用了防腐涂层,但腐蚀故障仍然是家常便饭。这些腐蚀失效归因于管道和其他金属结构所处的环境条件。本研究研究了碳钢管道(流管)在五种不同的环境条件下,涂有不同的防腐蚀剂,承受不同的温度和pH值时的劣化速率(腐蚀速率)。在实验室模拟了5种不同敷设管道的环境条件(表层土+淡水、海水床砂+海水、泻湖水、海水、0.5M NaCl溶液)。采用不同的70克(70g)碳钢管道样品作为试样。采用氧化红油漆和沥青漆作为防腐蚀剂。用水浴调节温度,用不同浓度的HCL和NaOH来改变ph值,用失重法计算腐蚀速率。结果表明:碳钢埋在土中比浸没在水中耐腐蚀性能好;海水中的腐蚀速率也高于盐度相对较小的泻湖水。腐蚀速率随温度的升高、盐度的升高、酸度和碱度的增加而增加。同样的环境条件下,沥青漆在碳钢管道上的防腐效果也优于氧化红漆。该研究将70g试样的腐蚀速率从悬浮在0.5M, NaCl溶液中的0.00127g/day降低到涂有沥青涂料的管道埋在干燥土壤中的0.000104g/day。
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Experimental Investigation of the Effects of Different Environmental Conditions on Pipelines Corrosion Rates
An estimate of about $18.5 million are expended by industries in Nigeria yearly on corrosion, the oil and gas industry takes more than 65% of this cost due to the peculiar nature of their facilities and operational conditions. In spite of the use of galvanized pipeline and application of the anti-corrosion coating of crude oil pipeline and other metallic structure in the oil and gas industry, corrosion failures are still daily occurrences. These corrosive failures have been attributed to the environmental conditions in which the pipeline and other metallic structures are located. This research studies the rate of deterioration (corrosion rate) of carbon steel pipeline (flow pipe) under five different environmental conditions, coated with different anti-corroding agents, and subjected to different temperatures and pH values. Five Different environmental conditions through which pipelines are laid (Top soil + Fresh water, Sea water bed sand + Sea water, Lagoon water, Seawater, NaCl solution (0.5M)) were simulated in the laboratory. Different seventy gram (70g) samples of the carbon steel pipeline were used as the coupon samples. Red oxide oil paint and tar paint were used as the anti-corroding agents. Water bath was used in regulating the temperature and different concentration of HCL and NaOH were used to vary the pH. Weight loss method was used to calculate the corrosion rates. Results show that carbon steel resists corrosion better when buried in soil than when submerged in water; also the corrosion rate is more in sea water than in the lagoon water of relatively smaller salinity. The rate of corrosion was observed to increase with: increase in temperature, increase in salinity, and increases in acidity and alkalinity. Also the tar paint is more effective as anti-corrodant than the red oxide oil paint when applied to the carbon steel pipeline under same environment conditions. The study successively reduced the corrosion rate of the 70g coupon sample from 0.00127g/day when the sample were suspended in 0.5M, NaCl solution to 0.000104g/day when pipeline coated with tar paint are buried in dry soil.
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