使用硫化氢清除剂减少污染和提高系统效率的全系统方法

J. A. Mcrae, Willem-Louis Marais, A. Jenkins
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摘要

Cotton Valley砂岩和Haynesville页岩地层位于美国德克萨斯州东部,在陆地上生产石油、天然气和凝析油。大多数生产资产已经成熟,并且正在酸化,并且在生产流体和气体中存在硫化氢,这不仅给生产设施中的固体沉积和资产完整性带来了操作问题,而且在考虑凝析油和天然气的加工、出口和销售时也带来了复杂性。采出气在LNG装置液化前,传统上采用MEA三嗪硫化氢清除剂进行处理。天然气中剩余的硫化氢含量和过程中的固体形成都存在历史问题,这威胁到液化天然气工厂的定期关闭。采用整体方法改进了整体脱硫工艺。这包括减少或消除固体的形成以及提高系统的清除效率。该方法考虑了当前的操作程序、系统参数、设备设计(接触器)和H2S清除剂的化学性质。
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Total Systems Approach to Reduce Fouling and Improve System Efficiency Using Hydrogen Sulfide Scavengers
The Cotton Valley sand and Haynesville shale formations are situated in East Texas, USA, producing oil, gas, and condensate on land. Most of the producing assets are mature and souring, and the presence of hydrogen sulfide in the produced fluids and gas provides both operational concerns in terms of solids deposition and asset integrity in the production facilities as well as complexity when considering the processing, export, and sale of condensate and gas. Produced gas was traditionally treated with MEA triazine hydrogen sulfide scavenger prior to liquification by LNG plant. There have been historical issues with both the levels of hydrogen sulfide left in the gas and also solids formation in the process, which threatened periodic shutdown of the LNG plant. A holistic approach was used to improve the overall sulfur removal process. This includes the reduction or elimination of solids formation as well as improvement in the system scavenging efficiency. The approach considered current operating procedures, system parameters, equipment design (contactors), and H2S scavenger chemistry.
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