多分散聚合物溶液二次维里系数的重整化基团评价

S. Stepanow, E. Straube
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引用次数: 1

摘要

2014利用重整化基团研究了两种单分散聚合物混合物的二次维里系数A2。发现交叉项A12有一个有限的极限,当其中一个聚合物的段数趋于无穷大时。这种行为预测A2的最大依赖于聚合物的相对组成。从我们的第一个rg计算得到的最大值超出了迄今为止实验研究的分子量比。J.体质快报46 (1985)L-1115 L-1122, 1985年12月,分类物理文摘36.20 61.40K 82.70
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Renormalization group evaluation of the second virial coefficient of polydisperse polymer solutions
2014 The second virial coefficient A2 for a mixture of two monodisperse polymers is studied by means of the renormalization group. It is found that the cross-term A12 has a finite limit if the segment number of one of the polymers tends to infinity. Such behaviour predicts a maximum of A2 in dependence on the relative composition of the polymers. The maximum resulting from our firstorder RG-calculation lies outside the molecular weight ratio investigated so far experimentally. J. Physique Lett. 46 (1985) L-1115 L-1122 ler DECEMBRE 1985, Classification Physics Abstracts 36.20 61.40K 82.70
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