碳填料对轮胎再生材料中张阻效应表现的影响研究

N. V. Shadrinov, K. P. Antoev
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摘要

展示了在实验室条件下获得的工业生产的轮胎再生材料RShT-4和Reg-1,以及导电碳填料为基础开发导电橡胶的机会。采用“Omsktehuglerod”有限公司生产的OMCARB CH85炭黑(CB)和Toho Tenax America公司生产的Tenax-e HTS-45碳纤维(CF)作为导电填料。研究了不同含量Santogard PVI和导电填料对再生材料的固化和流变特性。再生材料的物理力学性能研究表明,在Reg-1和RShT-4中引入和增加导电性CB和CF含量,导致断裂伸长率逐渐降低,抗拉强度和邵氏硬度增加,这是填料增强作用的证据。研究了导电填料含量对再生材料抗张性的影响。结果表明,在Reg-1和RSHT-4中加入导电性CB,可提高其导电性和张电阻率,即压缩电阻降低。添加CF会导致相反的效果——压缩电阻的增加。提出了引入导电炭黑时出现张阻和引入CF时电导率下降的可能机理。
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Investigation of the influence of carbon fillers on the manifestation of the effect of tensoresistivity in tire regenerates
An opportunity of development of electrically conductive rubber based on industrially produced tyre regenerate RShT-4 and Reg-1, obtained in laboratory conditions, with electrically conductive carbon fillers is shown. OMCARB CH85 carbon black (CB) produced by “Omsktehuglerod” Ltd. and Tenax-e HTS-45 carbon fibres (CF) produced by Toho Tenax America were used as electrically conductive fillers. Curing and rheometric properties of regenerates with different content of Santogard PVI and electroconductive fillers have been investigated. The study of physical and mechanical properties of regenerates has shown that introduction and increase of electroconductive CB and CF content in Reg-1 and RShT-4 leads to gradual reduction of elongation at break and increase in tensile strength and Shore A hardness, which is evidence of reinforcing effect of fillers. The effect of tensoresistance in the obtained regenerates depending on the content of electroconductive fillers is investigated. It is shown that addition of electroconductive CB to Reg-1 and RSHT-4 gives electroconductivity and tensoresistivity, that is, decrease of resistance in compression. Addition of CF leads to the opposite effect - increase of electrical resistance in compression. The possible mechanisms for the manifistation of tensoresistance at introduction of electroconductive CB and decrease of electroconductivity at introduction of CF are offered.
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