Şebnem Yezdan Pekçioğlu, C. Uraz, Selmin Yanar Ocaktan, Olcay Zunal
{"title":"天然沸石改性制备防腐涂料","authors":"Şebnem Yezdan Pekçioğlu, C. Uraz, Selmin Yanar Ocaktan, Olcay Zunal","doi":"10.30492/IJCCE.2021.135782.4416","DOIUrl":null,"url":null,"abstract":"Metal surface coating occupies an important place in industry. The most important external factor on metal surfaces is corrosion. Corrosion is a natural process that occurs because of chemical reaction between the metal surfaces and the medium. It causes degradation of metals. There are three methods that used for the prevent corrosion. These methods are cathodic protection, anodic protection, and barrier coatings. In this study, it was aimed to develop environmentally friendly corrosion resistant paint for the barrier coatings, by using zeolite material which has natural characteristic of corrosion resistant. In other words, it was aimed to gain the anticorrosive effect to the production of corrosion resistant paint by adding modified natural zeolite in paint. Micro scale zeolite was modified by using lanthanum (III) nitrate, zinc acetate and magnesium chloride solutions. The best results were obtained with a zeolite size of 0.8869 μm and using a 60% zeolite / solution volume ratio. It can be said from the results of the experiments that; thin zeolite film applications are very successful for corrosion resistance paint production. Modified natural zeolite coatings show very good ability to protect surfaces from corrosion. Results of these procedures are positive and promising. The best result is obtained by zeolite with size reduction and 60% zeolite/solution by volume ratio. The amount of zinc phosphate was greatly reduced. High and low content of zinc phosphates have almost the same anticorrosive effect with zeolite modified paint formulations. As a result, cation-exchanged zeolites can be considered as a safe and efficient alternative to traditional hazardous pigments in protecting steel surfaces.","PeriodicalId":14572,"journal":{"name":"Iranian Journal of Chemistry & Chemical Engineering-international English Edition","volume":"45 1","pages":""},"PeriodicalIF":1.0000,"publicationDate":"2021-11-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"MODIFICATION OF NATURAL ZEOLITE FOR ANTICORROSIVE PAINT PREPARATION\",\"authors\":\"Şebnem Yezdan Pekçioğlu, C. Uraz, Selmin Yanar Ocaktan, Olcay Zunal\",\"doi\":\"10.30492/IJCCE.2021.135782.4416\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Metal surface coating occupies an important place in industry. The most important external factor on metal surfaces is corrosion. Corrosion is a natural process that occurs because of chemical reaction between the metal surfaces and the medium. It causes degradation of metals. There are three methods that used for the prevent corrosion. These methods are cathodic protection, anodic protection, and barrier coatings. In this study, it was aimed to develop environmentally friendly corrosion resistant paint for the barrier coatings, by using zeolite material which has natural characteristic of corrosion resistant. In other words, it was aimed to gain the anticorrosive effect to the production of corrosion resistant paint by adding modified natural zeolite in paint. Micro scale zeolite was modified by using lanthanum (III) nitrate, zinc acetate and magnesium chloride solutions. The best results were obtained with a zeolite size of 0.8869 μm and using a 60% zeolite / solution volume ratio. It can be said from the results of the experiments that; thin zeolite film applications are very successful for corrosion resistance paint production. Modified natural zeolite coatings show very good ability to protect surfaces from corrosion. Results of these procedures are positive and promising. The best result is obtained by zeolite with size reduction and 60% zeolite/solution by volume ratio. The amount of zinc phosphate was greatly reduced. High and low content of zinc phosphates have almost the same anticorrosive effect with zeolite modified paint formulations. As a result, cation-exchanged zeolites can be considered as a safe and efficient alternative to traditional hazardous pigments in protecting steel surfaces.\",\"PeriodicalId\":14572,\"journal\":{\"name\":\"Iranian Journal of Chemistry & Chemical Engineering-international English Edition\",\"volume\":\"45 1\",\"pages\":\"\"},\"PeriodicalIF\":1.0000,\"publicationDate\":\"2021-11-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Iranian Journal of Chemistry & Chemical Engineering-international English Edition\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.30492/IJCCE.2021.135782.4416\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Iranian Journal of Chemistry & Chemical Engineering-international English Edition","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.30492/IJCCE.2021.135782.4416","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
MODIFICATION OF NATURAL ZEOLITE FOR ANTICORROSIVE PAINT PREPARATION
Metal surface coating occupies an important place in industry. The most important external factor on metal surfaces is corrosion. Corrosion is a natural process that occurs because of chemical reaction between the metal surfaces and the medium. It causes degradation of metals. There are three methods that used for the prevent corrosion. These methods are cathodic protection, anodic protection, and barrier coatings. In this study, it was aimed to develop environmentally friendly corrosion resistant paint for the barrier coatings, by using zeolite material which has natural characteristic of corrosion resistant. In other words, it was aimed to gain the anticorrosive effect to the production of corrosion resistant paint by adding modified natural zeolite in paint. Micro scale zeolite was modified by using lanthanum (III) nitrate, zinc acetate and magnesium chloride solutions. The best results were obtained with a zeolite size of 0.8869 μm and using a 60% zeolite / solution volume ratio. It can be said from the results of the experiments that; thin zeolite film applications are very successful for corrosion resistance paint production. Modified natural zeolite coatings show very good ability to protect surfaces from corrosion. Results of these procedures are positive and promising. The best result is obtained by zeolite with size reduction and 60% zeolite/solution by volume ratio. The amount of zinc phosphate was greatly reduced. High and low content of zinc phosphates have almost the same anticorrosive effect with zeolite modified paint formulations. As a result, cation-exchanged zeolites can be considered as a safe and efficient alternative to traditional hazardous pigments in protecting steel surfaces.
期刊介绍:
The aim of the Iranian Journal of Chemistry and Chemical Engineering is to foster the growth of educational, scientific and Industrial Research activities among chemists and chemical engineers and to provide a medium for mutual communication and relations between Iranian academia and the industry on the one hand, and the world the scientific community on the other.