天然沸石改性制备防腐涂料

IF 1 4区 工程技术 Q4 CHEMISTRY, MULTIDISCIPLINARY Iranian Journal of Chemistry & Chemical Engineering-international English Edition Pub Date : 2021-11-03 DOI:10.30492/IJCCE.2021.135782.4416
Şebnem Yezdan Pekçioğlu, C. Uraz, Selmin Yanar Ocaktan, Olcay Zunal
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引用次数: 0

摘要

金属表面涂层在工业中占有重要地位。金属表面最重要的外部因素是腐蚀。腐蚀是金属表面与介质发生化学反应而产生的自然过程。它会导致金属的降解。有三种防止腐蚀的方法。这些方法是阴极保护、阳极保护和屏障涂层。本研究旨在利用具有天然耐腐蚀特性的沸石材料,开发环境友好的屏障涂料耐腐蚀涂料。也就是说,在涂料中加入改性天然沸石,以达到生产耐腐蚀涂料的防腐效果。采用硝酸镧、乙酸锌和氯化镁溶液对微沸石进行了改性。沸石粒径为0.8869 μm,沸石/溶液体积比为60%时效果最佳。从实验结果可以看出;沸石薄膜在耐腐蚀涂料生产中的应用非常成功。改性天然沸石涂层具有很好的表面防腐能力。这些程序的结果是积极的和有希望的。沸石还原剂和沸石/溶液体积比为60%时效果最好。磷酸锌的用量大大减少。高含量和低含量的磷酸锌对沸石改性涂料的防腐效果几乎相同。因此,阳离子交换沸石可以被认为是一种安全有效的替代传统的有害颜料来保护钢铁表面。
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MODIFICATION OF NATURAL ZEOLITE FOR ANTICORROSIVE PAINT PREPARATION
Metal surface coating occupies an important place in industry. The most important external factor on metal surfaces is corrosion. Corrosion is a natural process that occurs because of chemical reaction between the metal surfaces and the medium. It causes degradation of metals. There are three methods that used for the prevent corrosion. These methods are cathodic protection, anodic protection, and barrier coatings. In this study, it was aimed to develop environmentally friendly corrosion resistant paint for the barrier coatings, by using zeolite material which has natural characteristic of corrosion resistant. In other words, it was aimed to gain the anticorrosive effect to the production of corrosion resistant paint by adding modified natural zeolite in paint. Micro scale zeolite was modified by using lanthanum (III) nitrate, zinc acetate and magnesium chloride solutions. The best results were obtained with a zeolite size of 0.8869 μm and using a 60% zeolite / solution volume ratio. It can be said from the results of the experiments that; thin zeolite film applications are very successful for corrosion resistance paint production. Modified natural zeolite coatings show very good ability to protect surfaces from corrosion. Results of these procedures are positive and promising. The best result is obtained by zeolite with size reduction and 60% zeolite/solution by volume ratio. The amount of zinc phosphate was greatly reduced. High and low content of zinc phosphates have almost the same anticorrosive effect with zeolite modified paint formulations. As a result, cation-exchanged zeolites can be considered as a safe and efficient alternative to traditional hazardous pigments in protecting steel surfaces.
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来源期刊
CiteScore
2.80
自引率
22.20%
发文量
0
审稿时长
6-12 weeks
期刊介绍: The aim of the Iranian Journal of Chemistry and Chemical Engineering is to foster the growth of educational, scientific and Industrial Research activities among chemists and chemical engineers and to provide a medium for mutual communication and relations between Iranian academia and the industry on the one hand, and the world the scientific community on the other.
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