正丁烯的骨架异构化

IF 9.3 2区化学 Q1 CHEMISTRY, PHYSICAL Catalysis Reviews-Science and Engineering Pub Date : 1997-11-01 DOI:10.1080/01614949708007099

J. Houžvička, V. Ponec

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引用次数: 100

摘要

本文综述了正丁烯骨架异构化与异丁烯骨架异构化最相关的几个方面:活性位点的性质、骨架异构化的主要机理以及骨架异构化与正丁烷骨架异构化的关系。结果表明，正丁烯骨架异构化的主要机理是单分子异构化(与丁烷异构化相反)，并且需要Br⊘嵌套酸(OH)活性位点。分子筛和分子筛的形状选择性影响分子筛的选择性和催化稳定性。这些影响是在对流行机制的了解的基础上解释的。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Skeletal Isomerization of n-Butene

Abstract In this review, the most relevant aspects of skeletal isomerization of n-butene to isobutene are discussed: the nature of the active sites, the prevailing mechanism of the skeletal isomerization, and the relation of this to that of n-butane. It is concluded that the prevailing mechanism of skeletal isomerization of n-butene is monomolecular (in contrast to butane isomerization) and requires Br⊘nsted acid (OH) active sites. The selectivity and catalytic stability can be influenced by the shape selectivity of zeolites and zeotypes. These effects are explained on the basis of the knowledge on the prevailing mechanism.

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来源期刊

Catalysis Reviews-Science and Engineering 化学-物理化学

CiteScore

22.30

自引率

2.80%

发文量

期刊介绍： Catalysis Reviews is dedicated to fostering interdisciplinary perspectives in catalytic science and engineering, catering to a global audience of industrial and academic researchers. This journal serves as a bridge between the realms of heterogeneous, homogeneous, and bio-catalysis, providing a crucial and critical evaluation of the current state of catalytic science and engineering. Published topics encompass advances in technology and theory, engineering and chemical aspects of catalytic reactions, reactor design, computer models, analytical tools, and statistical evaluations.