基辅科学电化学学校

V. Pekhnyo, A. Omel’chuk, O. Linyucheva
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引用次数: 0

摘要

概述了由基辅的科学机构和高等教育机构发起的电化学领域的科学研究方向和取得的成果。O.V. Plotnikov院士是世界知名的基辅电化学学院的先驱,该学院成立于上世纪二十年代:M.I. Usanovych, V.O. Izbekov, Ya.A.。Fialkov Yu.K。Delimarskyi, I.A. Sheka,以及许多其他科学界所熟知的科学家。O.V. Plotnikov和他的追随者是第一批尝试将当时最先进的电解解离理论、溶液化学理论和复杂化合物化学结合起来的人。基辅电化学学院在溶液化学理论、酸碱相互作用(Usanovich理论)、双电层结构(叶辛-马尔可夫效应、电位降安特罗波夫尺度)、熔融电解质的物理化学和电化学、电极过程动力学、电冶金学、电化学材料科学、电化学动力工程等基础研究方面取得了世界性的成就。我们学院的代表们极大地扩展了熔融电解质在电化学系统中的传质知识(金属从阳极转移到阴极的现象)。重有色金属(铋、铅、铟等)的获取和提炼、金属表面精加工、放射性核素提取、电镀技术、环境监测等新工艺已被引入工业生产实践。电化学材料科学的研究与解决电化学能源问题密切相关,特别是创造新的电流来源,包括固态、氢发生器和太阳能转换成电能。从天然原料中提取一些难熔金属,创造具有特定功能特性的新材料,催化剂和电催化剂,最新的电镀层,化学电流源和超级电容器的电极和电解质材料,有价值的无机化合物,金属和碳纳米相,缓蚀剂等电化学方面的研究正在扩大电化学材料科学的科学方向。
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SCIENTIFIC ELECTROCHEMICAL SCHOOL OF KYIV
An overview dedicates to the directions of scientific research and achieved results in the field of electrochemistry, initiated by scientific institutions and in higher educational institutions of Kyiv. Academician O.V. Plotnikov is the forerunner of the world- known Kyiv School of Electrochemistry, formed in the last century's twenties: M.I. Usanovych, V.O. Izbekov, Ya.A. Fialkov, Yu.K. Delimarskyi, I.A. Sheka, and many other scientists known to the general scientific community. O.V. Plotnikov and his followers are one of the first to attempt to combine the most progressive theoretical provisions on electrolytic dissociation, the chemical theory of solutions, and the chemistry of complex compounds for that time. World achievements of the Kyiv School of Electrochemistry were provided by the results of such fundamental research as the chemical theory of solutions, acid-base interactions (Usanovich's theory), the structure of the electric double layer (the Yesin-Markov effect, the reduced Antropov scale of potentials), physical chemistry and electrochemistry of molten electrolytes, kine­tics electrode processes, electrometallurgy, electrochemical materials science, electrochemical power engineering.  Representatives of our School significantly expanded the knowledge of mass transfer in electrochemical systems with molten electrolytes (the phenomenon of the transfer of metals from the anode to the cathode). New technological processes of obtaining and refining heavy non-ferrous metals (bismuth, lead, indium, etc.), finishing metal surfaces, extraction of radionuclides, electroplating technology, and environmental monitoring have been introduced into the practice of industrial production. Research in electrochemical materials science is closely connected to solving the problems of electrochemical energy, particularly, the creation of new sources of current, including solid-state, hydrogen generators, and converters of solar energy into electrical power. The studies of electrochemical aspects of the extraction of some refractory metals from natural raw materials, the creation of new materials with specified functional properties, catalysts, and electrocatalysts, the latest galvanic coatings, electrode and electrolyte materials for chemical current sources and supercapacitors, valuable inorganic compounds, metal and carbon nanophases, corrosion inhibitors are expanding the scientific direction of elect­rochemical materials science.
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