SiC/Si-W-Mo涂层在1873 K下保护C/C复合材料

Dangshe Hou, Kezhi Li, Hejun Li, Qiangang Fu, Yulei Zhang
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引用次数: 2

摘要

为了防止碳/碳复合材料在1873 K时发生氧化,采用两步包埋胶结技术制备了一种高效的抗氧化SiC/Si-W-Mo涂层。采用扫描电子显微镜(SEM)和x射线衍射仪(XRD)研究了复合涂层的微观结构和相组成。由α-SiC、Si和(WxMo1-x)Si2组成致密的复合涂层。氧化试验表明,在1873 K空气中氧化102 h,在1873 K至室温之间热循环10次后,SiC/Si-W-Mo涂层C/C复合材料的失重率仅为0.26%。多层涂层失效的原因是涂层中形成了可穿透的裂纹。
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SiC/Si-W-Mo coating for protection of C/C composites at 1873 K

In order to prevent carbon/carbon composites from oxidation at 1873 K, an efficient oxidation protective SiC/Si-W-Mo coating was prepared by a two-step pack cementation technique. The microstructures and the phase composition of the as-received multi-coating were examined by scanning electron microscopy (SEM) and X-ray diffraction (XRD). It is seen that the compact multi-coating is composed of α-SiC, Si, and (WxMo1–x)Si2. Oxidation test shows that, after oxidation at 1873 K in air for 102 h and thermal cycling between 1873 K and room temperature for 10 times, the weight loss of the SiC/Si-W-Mo coated C/C composites is only 0.26%. The invalidation of the multi-coating is attributed to the formation of penetrable cracks in the coating.

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