有机硅酸盐与缓蚀剂复合防腐涂料的电化学性能

A. Ivanova, L. N. Krasilnikova, O. Lezova, O. A. Zagrebelny, R. Khodzhaev, T. V. Khamova, V. Trusov, O. Shilova
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摘要

研究了常压缓蚀剂noh、N-M-1、FMT和磷化底漆VL-02对有机硅酸盐新改性OS-51-03M型防腐涂料电化学性能的影响。采用动电位极化法进行腐蚀试验,采用St3sp5牌号碳钢板,采用油漆和清漆法进行涂层。结果表明,磷酸盐组合物noh和缓蚀剂N-M-1显著提高了有机硅酸盐涂层在3% NaCl腐蚀环境中的耐蚀性。对于这些涂层,在腐蚀环境中暴露1个月后,不可能记录电流和腐蚀电位。在相似的测量条件下,记录了未改性有机硅酸盐涂层钢板的电化学参数,腐蚀电流密度为8·10-9A/m2,腐蚀电位为- 144 mV。结果表明,磷化底漆VL-02对提高有机硅酸盐涂层体系防腐保护期的作用可以忽略不计。确定了大气缓蚀剂的抑制保护类型。
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Electrochemical properties of anticorrosive coatings based on organosilicate composition in combination with corrosion inhibitors
The article considers the effect of atmospheric corrosion inhibitors “NOTEH”, “N-M-1”, “FMT” and phosphating primer VL-02 on the electrochemical properties of anticorrosive coatings based on a new modification of the organosilicate composition — brand OS-51-03M. For corrosion tests using the method of potentiodynamic polarization, carbon steel plates of the St3sp5 brand were used, on which coatings were applied by the paint and varnish method. It was revealed that the aqueous phosphating composition “NOTEH” and the corrosion inhibitor “N-M-1” significantly increase the corrosion resistance of organosilicate coatings in an aggressive environment — 3 % NaCl solution. For these coatings, it is impossible to register the current and corrosion potential after 1 month of exposure of coatings in a corrosive environment. Under similar measurement conditions, the electrochemical parameters of steel plates with unmodified organosilicate coating were recorded — the corrosion current density and corrosion potential were equal to 8·10-9A/m2 and –144 mV, respectively. It was revealed that the phosphating primer VL-02 has a negligible effect on increasing the duration of anticorrosive protection of the organosilicate coating system. The type of inhibitory protection of atmospheric corrosion inhibitors has been determined.
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