化学反应过程中的化学势和产热

F. Diederichs
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摘要

这项研究的一个主要目标是展示化学和生化反应是如何发生的。由于通过反应发生的大部分能量转换总是与电位差的变化有关,因此这些现象学事件最初也处于前景。然而,除了这些能量变化之外,熵的变化也很重要。这里,特别强调的是对交换熵和产生熵的区分。与机械能或电能的转换相比,化学反应中的能量转换为热能占有特殊的地位,因为前者不涉及力。使用通过通道的传递反应,该过程可以用简化形式表示。很明显,热量的产生是通过能量过渡态发生的,而正是这种产生的热量本身导致了多重性的显著增加。因此,反应过程得以进行。结论是,在化学和生化反应中,不是一种力,而是多样性决定了这些过程的方向和过程。
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Chemical Potentials and Heat Production in the Course of Chemical Reactions
A major goal of this study is to show how chemical and biochemical reactions occur. Since a large part of the energy transformations occurring via a reaction is always related to changes in potential differences, these phenomenological events are initially also in the foreground. In addition to these energetic changes, however, entropic changes are also important. Here, special emphasis is placed on distinguishing between exchanged and produced entropy. The conversion of energy in chemical reactions into heat energy occupies a special position compared to the conversions of e.g. mechanical or electrical energy in that no forces are involved in the former. Using transport reactions through channels, the process can be expressed in a simplified form. It is made clear that heat generation occurs via energetic transition states, and that it is this generated heat itself that leads to a significant increase in multiplicity. As a result, the reaction process is allowed to take place. The conclusion is that in chemical and biochemical reactions, instead of a force, multiplicity determines the direction and course of such processes.
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