回收高纯度对苯二甲酸的研究

Chaonan Liu, Weihong Xia, C. Ping, Chunmei Gao
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引用次数: 0

摘要

在传统的碱减重废水处理方法中,对COD的去除考虑较多,而对有价值资源的回收则较少考虑。本研究采用混凝沉淀法提纯母液,从碱减重中回收高纯TA。通过各种方法对所得TA的性质进行了研究,结果表明,在废水pH 7.0 ~ 7.5、Al2(SO4)3.18H2O投加量为300 ~ 400mg/l的条件下,混凝沉淀得到的TA纯度有较大提高,回收率高,热重分析(TGA)谱图也证实了这一点。粒度分析表明,回收的TA晶粒尺寸变大,杂质含量少。因此混凝沉淀法是一种有效的预处理方法。该研究对PET的回收利用和TA工业废水的处理具有一定的指导意义。
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Notice of RetractionThe Study on Recovery of Highly Purified Terephthalic Acid
In those traditional ways of treating alkali weight reduction wastewater, the COD removal is greatly considered, while recovering the valuable resource according to the principles of sustainable development is less involved. In this study, the recovery of high pure TA from alkali weight-reduction has been researched by purified mother liquid with coagulation sedimentation. The characters of TA obtained was investigated by various methods, results has shown that the purity of TA was great improved in view of high recovery rate by coagulation sedimentation on conditions of pH 7.0-7.5 of wastewater and 300-400mg/l in quantity of Al2(SO4)3.18H2O, thermogravimetric analysis (TGA) spectrums proved this. Particle size analysis revealed the crystal size of recovered TA became greater, it contained few impurities. So coagulation-sedimentation by pretreatment is an effective method. The study is also very useful in recycling of PET and treating TA industrial wastewater.
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