G. Keglevich, Henrietta Forintos, T. Körtvélyesi, L. Tőke,
{"title":"芳基膦氧化物与二甲基乙炔二羧酸酯(DMAD)[2+2]环加成形成的氧膦烯的逆Wittig反应","authors":"G. Keglevich, Henrietta Forintos, T. Körtvélyesi, L. Tőke,","doi":"10.1039/B108675H","DOIUrl":null,"url":null,"abstract":"The intermediate oxaphosphetenes 2 formed by the novel cycloaddition of the PO group of arylphosphine oxides 1 and the acetylene moiety of DMAD are stabilised by an inverse Wittig reaction to afford the corresponding stabilised phosphonium ylide 3.","PeriodicalId":17267,"journal":{"name":"Journal of The Chemical Society-perkin Transactions 1","volume":"34 1","pages":"26-27"},"PeriodicalIF":0.0000,"publicationDate":"2002-12-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"11","resultStr":"{\"title\":\"Inverse Wittig reaction of oxaphosphetenes formed by the [2+2] cycloaddition of arylphosphine oxides and dimethyl acetylenedicarboxylate (DMAD)\",\"authors\":\"G. Keglevich, Henrietta Forintos, T. Körtvélyesi, L. Tőke,\",\"doi\":\"10.1039/B108675H\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The intermediate oxaphosphetenes 2 formed by the novel cycloaddition of the PO group of arylphosphine oxides 1 and the acetylene moiety of DMAD are stabilised by an inverse Wittig reaction to afford the corresponding stabilised phosphonium ylide 3.\",\"PeriodicalId\":17267,\"journal\":{\"name\":\"Journal of The Chemical Society-perkin Transactions 1\",\"volume\":\"34 1\",\"pages\":\"26-27\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2002-12-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"11\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society-perkin Transactions 1\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/B108675H\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society-perkin Transactions 1","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/B108675H","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Inverse Wittig reaction of oxaphosphetenes formed by the [2+2] cycloaddition of arylphosphine oxides and dimethyl acetylenedicarboxylate (DMAD)
The intermediate oxaphosphetenes 2 formed by the novel cycloaddition of the PO group of arylphosphine oxides 1 and the acetylene moiety of DMAD are stabilised by an inverse Wittig reaction to afford the corresponding stabilised phosphonium ylide 3.
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