杯[4]芳烃和卟啉系四手性五元环碳酸盐的合成。

Enantiomer Pub Date : 2002-03-01 DOI:10.1080/10242430212195
T. Takata, H. Takagi, Yoshio Furusho
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引用次数: 4

摘要

以杯[4]芳烃对叔丁基杯[4]芳烃1a为原料,用(R)-缩水甘油酯进行o -缩水甘油化反应,然后在溴化锂催化下用二氧化碳羰基化,合成杯[4]芳烃系四手性五元环碳酸酯1c。卟啉系链手性五元环碳酸酯2c也用类似方法合成。
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Synthesis of calix[4]arene and porphyrin tethering four chiral five-membered cyclic carbonates.
Calix[4]arene tethering four chiral five-membered cyclic carbonates 1c was synthesized by O-glycidylation of p-tert-butylcalix[4]arene 1a with (R)-glycidyl tosylate, followed by carbonation with carbon dioxide catalyzed by lithium bromide. Porphyrin tethering chiral five-membered cyclic carbonates 2c was similarly synthesized.
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