掺银BaTiO3导电粉体的制备与表征

S. Hao, D. Fu, Jialong Li, Wen Wang, B. Shen
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引用次数: 12

摘要

采用溶胶-凝胶法制备了不同Ag/Ba摩尔比掺杂银的BaTiO3粉体。当银浓度为0.10(%)时,粉末在800℃和500℃下进行两次煅烧,其电阻率达到最低点5.644 Ω·m。XRD和FTIR研究表明,掺杂和煅烧过程没有形成新的物质,但改性BaTiO3晶体的粒度和Ti-O键强度都发生了变化。利用缺陷理论讨论了不同银浓度和不同制备方法的掺银钛酸钡粉体的电导率。
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Preparation and Characterization of Ag-Doped BaTiO3 Conductive Powders
BaTiO3 powders doped with Ag at different Ag/Ba molar ratios were prepared by sol-gel method. The resistivity reached the lowest point of 5.644 Ω·m when Ag concentration was 0.10 at% and the powders were calcined for two times at 800°C and 500°C. XRD and FTIR investigations showed that no new substance was formed after the doping and calcining process, but the particle size and the strength of Ti-O bond in modified BaTiO3 crystal cell all changed. The conductivity of Ag-doped BaTiO3 powders with different Ag concentrations and through different preparing methods was discussed by using defect theory.
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