短波近红外光电二极管阵列仪器之间的校准传递

C. Hayes, K. Walsh, R. Lerud
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引用次数: 0

摘要

作者摘要:比较了在短波近红外硅光电二极管阵列仪器之间移植完整芒果干物质含量偏最小二乘模型的方法。方法包括使用平均差谱进行偏置调整、新的像素到波长分配、分段直接标准化(PDS)、全局模型、模型更新(MU)以及这些方法的组合。在校准集和转移集中使用相同品种的PDS获得了最佳结果(R2 > 0.84,偏差< 0.2)。如果从属单元的波长精度令人满意,那么苹果光谱转移集的使用也是成功的。另外,给出可接受预测结果的现场实际解决方案涉及跨单元开发全球模型或通过包含新种群的光谱来更新模型,使用使用主单元估计的参考值。
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Calibration transfer between short wave near infrared photodiode array instruments
Author Summary: Transfer methods were compared for the porting of partial least squares models for intact mango dry matter content between short wave near infrared silicon photodiode array instruments. Methods included bias adjustment using average difference spectrum, new pixel-to-wavelength assignments, piecewise direct standardisation (PDS), global models, model updating (MU) and combinations of these. Best results (R2 > 0.84 and bias < 0.2) were obtained by PDS using the same variety of fruit in calibration and transfer sets. The use of an apple spectra transfer set was also successful, if the wavelength accuracy of the slave unit(s) is satisfactory. Alternatively, a field practical solution that gave acceptable prediction results involved development of a global model across units or model updating by inclusion of spectra of the new population, using reference values estimated using the master unit.
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