Mechanical Behavior of Yttria-Stabilized Zirconia Aqueous Cast Tapes and Laminates

Aqueous tape casting was used to produce yttria-stabilized zirconia films for electrolyte-supported solid oxide fuel cell (SOFC). Tape casting slurries were prepared varying the binder content between 20 and 25 wt%. A commercial acrylic emulsion served as binder. Rheological measurements of the two slurries were performed. Both slurries showed a shear-thinning behavior. Tapes with 25 wt% binder exhibited adequate flexibility and a smooth and homogeneous surface, free of cracks and other defects. Suitable conditions of lamination were found and a theoretical density of 54% in the laminates was achieved. Laminated tapes showed higher tensile strength compared to single sheets. Tape orientation has a significant influence on the mechanical properties. Tensile strength, elongation to strain, and Young’s modulus measured in samples produced in the direction of casting showed higher property values.