基于连续小波分解的红外吸收光谱特异性识别技术

IF 0.8 4区 化学 Q4 SPECTROSCOPY Spectroscopy Pub Date : 2022-08-01 DOI:10.56530/spectroscopy.mz7490j2
Yongbo Yu, Houfei Shang, Z. Du, N. Gao, Jinyi Li, Zhaozong Meng, Zonghua Zhang
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引用次数: 0

摘要

红外吸收光谱技术由于具有灵敏度高、抗干扰能力强的特点,在气体检测中得到了广泛的应用。为解决气体检测中的谱线混叠问题,研究了基于时频分析的红外吸收光谱技术在成分识别中的应用。对红外吸收光谱的二阶导数谱进行连续小波变换,得到时频特征矩阵。通过小波系数的方差选择合适的尺度范围。利用时频特性矩阵中时间和频率的相关分析进行成分识别。实验结果表明,对时间维度进行相关分析可以提取待测气体在混合气体中的特征吸收位置。与全光谱区间的频率相关分析相比,在特征吸收位置进行频率相关分析可以提高识别精度。本文的研究为气体的定量检测提供了新的思路。
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Specific Recognition Technology of Infrared Absorption Spectra Based on Continuous Wavelet Decomposition
Because infrared (IR) absorption spectroscopy technology can offer high sensitivity and strong anti-interference capabilities, it is widely used in gas detection. To solve the problem of spectrum line aliasing in gas detection, this study examined the application of IR absorption spectroscopy technology based on time-frequency analysis in component identification. The second derivative spectrum of the IR absorption spectroscopy was processed by continuous wavelet transform to obtain the time-frequency characteristic matrix. The appropriate scale range was selected through the variance of wavelet coefficients. The correlation analysis of time and frequency on the time-frequency characteristic matrix was used for component identification. The experimental results showed that the correlation analysis of the time dimension can extract the characteristic absorption position of the gas to be measured in the gas mixture. The frequency correlation analysis at the characteristic absorption position can improve the recognition accuracy compared with the frequency correlation analysis in the entire spectral interval. The research in this article provides new ideas for the quantitative detection of gases.
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来源期刊
Spectroscopy
Spectroscopy 物理-光谱学
CiteScore
1.10
自引率
0.00%
发文量
0
审稿时长
3 months
期刊介绍: Spectroscopy welcomes manuscripts that describe techniques and applications of all forms of spectroscopy and that are of immediate interest to users in industry, academia, and government.
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