{"title":"沸石中的过渡金属离子:Cu2+的定位和能量学","authors":"R. Schoonheydt","doi":"10.1080/01614949308013908","DOIUrl":null,"url":null,"abstract":"Abstract In this review only exchangeable cations on extralattice positions in zeolites are considered. Cu2+ is used as a probe for the siting, the nature, and the energy of the bonding to the lattice. The term zeolite encompasses the crystalline aluminosilicates and the crystalline aluminum phosphates (ALPO) with ion exchange and molecular sieving properties. However, exchangeable cations in isomorphously substituted ALPOs have not been studied systematically and are not treated here.","PeriodicalId":50986,"journal":{"name":"Catalysis Reviews-Science and Engineering","volume":"6 1","pages":"129-168"},"PeriodicalIF":9.3000,"publicationDate":"1993-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"152","resultStr":"{\"title\":\"Transition metal ions in zeolites: siting and energetics of Cu2+\",\"authors\":\"R. Schoonheydt\",\"doi\":\"10.1080/01614949308013908\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract In this review only exchangeable cations on extralattice positions in zeolites are considered. Cu2+ is used as a probe for the siting, the nature, and the energy of the bonding to the lattice. The term zeolite encompasses the crystalline aluminosilicates and the crystalline aluminum phosphates (ALPO) with ion exchange and molecular sieving properties. However, exchangeable cations in isomorphously substituted ALPOs have not been studied systematically and are not treated here.\",\"PeriodicalId\":50986,\"journal\":{\"name\":\"Catalysis Reviews-Science and Engineering\",\"volume\":\"6 1\",\"pages\":\"129-168\"},\"PeriodicalIF\":9.3000,\"publicationDate\":\"1993-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"152\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Catalysis Reviews-Science and Engineering\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1080/01614949308013908\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis Reviews-Science and Engineering","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1080/01614949308013908","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Transition metal ions in zeolites: siting and energetics of Cu2+
Abstract In this review only exchangeable cations on extralattice positions in zeolites are considered. Cu2+ is used as a probe for the siting, the nature, and the energy of the bonding to the lattice. The term zeolite encompasses the crystalline aluminosilicates and the crystalline aluminum phosphates (ALPO) with ion exchange and molecular sieving properties. However, exchangeable cations in isomorphously substituted ALPOs have not been studied systematically and are not treated here.
期刊介绍：
Catalysis Reviews is dedicated to fostering interdisciplinary perspectives in catalytic science and engineering, catering to a global audience of industrial and academic researchers. This journal serves as a bridge between the realms of heterogeneous, homogeneous, and bio-catalysis, providing a crucial and critical evaluation of the current state of catalytic science and engineering. Published topics encompass advances in technology and theory, engineering and chemical aspects of catalytic reactions, reactor design, computer models, analytical tools, and statistical evaluations.
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