{"title":"在含有三乙醇胺和盐酸硫胺的酸性硫酸盐浴中电沉积Zn-Co合金","authors":"V. Narasimhamurthy, L. H. Shivashankarappa","doi":"10.30799/JACS.228.21070101","DOIUrl":null,"url":null,"abstract":"Article history: Received 07 December 2020 Accepted 27 December 2020 Available online 17 January 2021 Electrodeposition of Zn-Co alloy from an acid sulphate bath has been carried out in this research work. The effects of metal ion ratio in the bath, pH current density, temperature, stirring, thickness and concentrations of triethanolamine and thiaminehydrochloride on the alloy composition and on cathodic current efficiency have been investigated. The deposition potentials of Zn-Co alloy are less noble of zinc and cobalt. The structure of Zn-Co alloy was investigated by X-ray diffraction indicates zinc structure. The surface morphology of alloy deposits is found to depend on the percentage of cobalt in the alloy. Under the optimum operating conditions, Zn-Co alloy deposition follows anomalous co-deposition.","PeriodicalId":14902,"journal":{"name":"Journal of Advanced Chemical Sciences","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2021-01-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Electrodeposition of Zn-Co Alloy from an Acid Sulphate Bath Containing Triethanolamine and Thiaminehydrochloride\",\"authors\":\"V. Narasimhamurthy, L. H. Shivashankarappa\",\"doi\":\"10.30799/JACS.228.21070101\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Article history: Received 07 December 2020 Accepted 27 December 2020 Available online 17 January 2021 Electrodeposition of Zn-Co alloy from an acid sulphate bath has been carried out in this research work. The effects of metal ion ratio in the bath, pH current density, temperature, stirring, thickness and concentrations of triethanolamine and thiaminehydrochloride on the alloy composition and on cathodic current efficiency have been investigated. The deposition potentials of Zn-Co alloy are less noble of zinc and cobalt. The structure of Zn-Co alloy was investigated by X-ray diffraction indicates zinc structure. The surface morphology of alloy deposits is found to depend on the percentage of cobalt in the alloy. Under the optimum operating conditions, Zn-Co alloy deposition follows anomalous co-deposition.\",\"PeriodicalId\":14902,\"journal\":{\"name\":\"Journal of Advanced Chemical Sciences\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2021-01-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Advanced Chemical Sciences\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.30799/JACS.228.21070101\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Advanced Chemical Sciences","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.30799/JACS.228.21070101","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Electrodeposition of Zn-Co Alloy from an Acid Sulphate Bath Containing Triethanolamine and Thiaminehydrochloride
Article history: Received 07 December 2020 Accepted 27 December 2020 Available online 17 January 2021 Electrodeposition of Zn-Co alloy from an acid sulphate bath has been carried out in this research work. The effects of metal ion ratio in the bath, pH current density, temperature, stirring, thickness and concentrations of triethanolamine and thiaminehydrochloride on the alloy composition and on cathodic current efficiency have been investigated. The deposition potentials of Zn-Co alloy are less noble of zinc and cobalt. The structure of Zn-Co alloy was investigated by X-ray diffraction indicates zinc structure. The surface morphology of alloy deposits is found to depend on the percentage of cobalt in the alloy. Under the optimum operating conditions, Zn-Co alloy deposition follows anomalous co-deposition.
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