球面近似在几种特定偶极晶体中的应用

M. Marrenga , Th. Niemeijer
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引用次数: 6

摘要

考虑了偶极-偶极相互作用的球面近似。给出了Ce2Mg3(NO3)12⋯24H2O和Dy(C2H⋯SO4)3⋯9H2O两种化合物的临界温度的数值计算。与实验数据吻合较好。Luttinger-Tisza计算显示出这两种化合物的精确经典基态,而该计算显示在Er(C2H5⋯SO4)3⋯9H2O中失败。我们发现,在某些系统中,远程效应可以通过在系统中引入额外的自由度来描述,因此临界行为类似于在四维晶格上具有短程相互作用的系统的临界行为。
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Application of the spherical approximation to several specific dipolar crystals

The spherical approximation is considered for dipole—dipole interactions. Numerical calculations of the critical temperature of two compounds, Ce2Mg3(NO3)12⋯24H2O and Dy(C2H⋯SO4)3 ⋯9H2O, are presented. Good agreement with experimental data is found. The Luttinger—Tisza calculations are shown to give the exact classical ground state in these two compounds, whereas this calculation is shown to fail in Er(C2H5⋯SO4)3⋯9H2O.

It is found that in some systems the longe-range effects can be described by introducing an extra degree of freedom in the system, and the critical behaviour is therefore similar to that of a system with short-range interactions on a four-dimensional lattice.

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