n -b-羟乙基油酰咪唑作为增效剂增强天然椰基肌氨酸对钢的防腐效果

Saad E. Kaskah, Gitta Ehrenhaft, J. Gollnick, C. Fischer
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引用次数: 2

摘要

为了研究天然衍生的椰基肌氨酸与n -b-羟乙基油酰咪唑在0.1 M NaCl中对CR4钢的防腐性能,采用了不同的评价体系(失重、电化学测量和喷雾腐蚀试验)。两种化合物在不同浓度(25-100 mmol/L)和不同浸涂时间(1-30分钟)下进行测试,先单独测试,然后联合测试,以检查其对表面保护的协同效应。如果单独使用,两者的缓蚀效果都不显著,在所有浓度和浸涂次数下的缓蚀效率都低于50%。相比之下,化合物组合显示出与较高浓度相关的更好的腐蚀抑制作用。在所有方法中,100 mmol/L的化合物组合浓度使重量测试的效率提高了83%,阻抗测量的效率提高了84%,动电位极化的效率提高了91%以上。浸渍涂层变化证明10分钟是所有化合物的最佳选择,化合物组合的最高效率高达86%。
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N-b-Hydroxyethyl Oleyl Imidazole as Synergist to Enhance the Corrosion Protection Effect of Natural Cocoyl Sarcosine on Steel
To investigate the corrosion protection behavior of naturally derived cocoyl sarcosine in combination with N-b-hydroxyethyl oleyl imidazole for steel CR4 in 0.1 M NaCl, different evaluation systems (weight loss, electrochemical measurements, and spray corrosion tests) were used. Both compounds were tested in different concentrations (25–100 mmol/L) and with variable dip coating times (1–30 min), first individually and then in combination, to check any synergistic effects for surface protection. Both showed only an insignificant corrosion inhibiting effect with less than 50% efficiency at all concentrations and dip coating times if used alone. In contrast, compound combinations revealed an improved corrosion inhibition correlated with higher concentrations. Across all methods, the compound combination concentration of 100 mmol/L resulted in improved efficiency of up to 83% for gravimetric tests, up to 84% for the impedance measure and more than 91% for potentiodynamic polarization. Dip coating variations proved 10 min to be the best option for all compounds with a maximum efficiency of up to 86% for the compound combination.
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