C. Song, Xiaohui Li, Wei Liu, Ziqing Cao, Yuanyuan Ren, Qichao Zhou, Li Zhang
{"title":"基于6-(3′，4′-二羧基-苯氧基)间苯二甲酸和4,4′-联吡啶混合配体的新型三节(3,4,6)连接镍(II)配位聚合物","authors":"C. Song, Xiaohui Li, Wei Liu, Ziqing Cao, Yuanyuan Ren, Qichao Zhou, Li Zhang","doi":"10.1080/15533174.2015.1137064","DOIUrl":null,"url":null,"abstract":"Reported here is a new Ni(II) compound, namely {Ni2(L)(bipy)2(H2O)2}n (1 H4L = 6-(3′,4′-dicarboxyl-phenoxy)isophthalic acid, bipy = 4,4′-bipyridine), which has been synthesized via the solvothermal reactions of Ni(NO3)2·6H2O, H4L and bipy. Single crystal X-ray analysis reveals that compound 1 crystallizes in triclinic P-1 space group with cell parameters a = 9.8887(6), b = 9.9884(4), c = 19.2310(11), α = 79.187(4), β = 83.862(5), γ = 80.708(4). The title compound features a three-dimensional (3D) framework and can be simplified into a trinodal (3,4,6)-connected topological network. Moreover, the thermal and luminescent properties of compound 1 were also investigated.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2016-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"A New Trinodal (3,4,6)-Connected Ni(II) Coordination Polymer Based on the Mixed Ligands of 6-(3′,4′-Dicarboxyl-Phenoxy) Isophthalic Acid and 4,4′-Bipyridine\",\"authors\":\"C. Song, Xiaohui Li, Wei Liu, Ziqing Cao, Yuanyuan Ren, Qichao Zhou, Li Zhang\",\"doi\":\"10.1080/15533174.2015.1137064\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Reported here is a new Ni(II) compound, namely {Ni2(L)(bipy)2(H2O)2}n (1 H4L = 6-(3′,4′-dicarboxyl-phenoxy)isophthalic acid, bipy = 4,4′-bipyridine), which has been synthesized via the solvothermal reactions of Ni(NO3)2·6H2O, H4L and bipy. Single crystal X-ray analysis reveals that compound 1 crystallizes in triclinic P-1 space group with cell parameters a = 9.8887(6), b = 9.9884(4), c = 19.2310(11), α = 79.187(4), β = 83.862(5), γ = 80.708(4). The title compound features a three-dimensional (3D) framework and can be simplified into a trinodal (3,4,6)-connected topological network. Moreover, the thermal and luminescent properties of compound 1 were also investigated.\",\"PeriodicalId\":22118,\"journal\":{\"name\":\"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2016-05-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/15533174.2015.1137064\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/15533174.2015.1137064","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
A New Trinodal (3,4,6)-Connected Ni(II) Coordination Polymer Based on the Mixed Ligands of 6-(3′,4′-Dicarboxyl-Phenoxy) Isophthalic Acid and 4,4′-Bipyridine
Reported here is a new Ni(II) compound, namely {Ni2(L)(bipy)2(H2O)2}n (1 H4L = 6-(3′,4′-dicarboxyl-phenoxy)isophthalic acid, bipy = 4,4′-bipyridine), which has been synthesized via the solvothermal reactions of Ni(NO3)2·6H2O, H4L and bipy. Single crystal X-ray analysis reveals that compound 1 crystallizes in triclinic P-1 space group with cell parameters a = 9.8887(6), b = 9.9884(4), c = 19.2310(11), α = 79.187(4), β = 83.862(5), γ = 80.708(4). The title compound features a three-dimensional (3D) framework and can be simplified into a trinodal (3,4,6)-connected topological network. Moreover, the thermal and luminescent properties of compound 1 were also investigated.
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