氧插入反应。五氧化二铬醚与四旋龙反应的再研究

J. Baldwin, J. Swallow, H. Chan
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引用次数: 24

摘要

与先前的报告相反,我们发现五氧化二铬醚溶液将四苯基环戊二酮氧化为已知的酮内酯,通过铬酸氧化可以更有效地获得酮内酯;我们一直无法准备之前声称的过氧化氢。
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Oxygen insertion reactions. A re-investigation of the reaction of chromium pentoxide etherate with tetracyclone
In contradiction to an earlier report we have found that chromium pentoxide etherate solution oxidises tetraphenylcyclopentadienone to a known keto-lactone, which can be obtained more efficiently by chromic acid oxidation; we have been unable to prepare the earlier claimed peroxide.
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