{"title":"氧插入反应。五氧化二铬醚与四旋龙反应的再研究","authors":"J. Baldwin, J. Swallow, H. Chan","doi":"10.1039/C29710001407","DOIUrl":null,"url":null,"abstract":"In contradiction to an earlier report we have found that chromium pentoxide etherate solution oxidises tetraphenylcyclopentadienone to a known keto-lactone, which can be obtained more efficiently by chromic acid oxidation; we have been unable to prepare the earlier claimed peroxide.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"17 1","pages":"1407-1408"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"24","resultStr":"{\"title\":\"Oxygen insertion reactions. A re-investigation of the reaction of chromium pentoxide etherate with tetracyclone\",\"authors\":\"J. Baldwin, J. Swallow, H. Chan\",\"doi\":\"10.1039/C29710001407\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In contradiction to an earlier report we have found that chromium pentoxide etherate solution oxidises tetraphenylcyclopentadienone to a known keto-lactone, which can be obtained more efficiently by chromic acid oxidation; we have been unable to prepare the earlier claimed peroxide.\",\"PeriodicalId\":17278,\"journal\":{\"name\":\"Journal of The Chemical Society D: Chemical Communications\",\"volume\":\"17 1\",\"pages\":\"1407-1408\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"24\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society D: Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C29710001407\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society D: Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C29710001407","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Oxygen insertion reactions. A re-investigation of the reaction of chromium pentoxide etherate with tetracyclone
In contradiction to an earlier report we have found that chromium pentoxide etherate solution oxidises tetraphenylcyclopentadienone to a known keto-lactone, which can be obtained more efficiently by chromic acid oxidation; we have been unable to prepare the earlier claimed peroxide.