{"title":"含氟芳香羧酸的Tb3+无水发光配合物的电化学合成","authors":"A. Oflidi","doi":"10.17677/fn20714807.2019.01.02","DOIUrl":null,"url":null,"abstract":"Electrochemical synthesis of terbium (III) waterless complex compounds with fluorine-containing aromatic carboxylic acids of TbL3 content was performed. The structure of obtained complex compounds coordination site was studied using the IR-spectroscopy method, and it was found out, that the coordination between used ligands and Tb3+ ions is bidentate. We also studied luminescent properties of the obtained compounds and showed that the terbium (III) with pentafluorobenzoic acid complex compound has the highest luminescent efficiency.","PeriodicalId":12217,"journal":{"name":"Fluorine Notes","volume":"27 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2019-02-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Electrochemical synthesis of Tb3+ waterless luminescent complex compounds with some fluorine-containing aromatic carboxylic acids\",\"authors\":\"A. Oflidi\",\"doi\":\"10.17677/fn20714807.2019.01.02\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Electrochemical synthesis of terbium (III) waterless complex compounds with fluorine-containing aromatic carboxylic acids of TbL3 content was performed. The structure of obtained complex compounds coordination site was studied using the IR-spectroscopy method, and it was found out, that the coordination between used ligands and Tb3+ ions is bidentate. We also studied luminescent properties of the obtained compounds and showed that the terbium (III) with pentafluorobenzoic acid complex compound has the highest luminescent efficiency.\",\"PeriodicalId\":12217,\"journal\":{\"name\":\"Fluorine Notes\",\"volume\":\"27 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2019-02-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Fluorine Notes\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.17677/fn20714807.2019.01.02\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Fluorine Notes","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.17677/fn20714807.2019.01.02","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Electrochemical synthesis of Tb3+ waterless luminescent complex compounds with some fluorine-containing aromatic carboxylic acids
Electrochemical synthesis of terbium (III) waterless complex compounds with fluorine-containing aromatic carboxylic acids of TbL3 content was performed. The structure of obtained complex compounds coordination site was studied using the IR-spectroscopy method, and it was found out, that the coordination between used ligands and Tb3+ ions is bidentate. We also studied luminescent properties of the obtained compounds and showed that the terbium (III) with pentafluorobenzoic acid complex compound has the highest luminescent efficiency.