用EDX-SEM研究伊朗磷矿形成矿物(萤石)的纳米级成分评价

F. Bolourchifard , A. Memar
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引用次数: 4

摘要

本文利用SEM-EDX在纳米尺度上对伊朗扎格罗斯山磷矿地质构造中形成磷矿的细粒矿物(钙石- ca5 (PO4,CO3)3F,OH)进行了检测、分析和解释。并将所得结果与XRD分析结果和样品在偏光显微镜下的直接观察结果进行了比较。寻找矿物中元素的组成是最好的探路者,在许多地质调查中也非常重要。细粒磷矿物充当了吸引某些元素的陷阱。但有时这些矿物质非常细,很难确定和分离它们以进行进一步的研究。例如,用单晶x射线衍射(single -crystal XRD)分析来解释和研究纳米尺度上的细矿物成分是不可能的。由于岩石样品中矿物相的多样性,对全元素分析结果的解释,例如XRF, ICP,并不那么真实。因此,用扫描电子显微镜(SEM)和能量色散x射线分析(EDX)对矿物进行研究是测定细粒造岩矿物中元素的最佳方法。
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The Study of Phosphate Rock Forming Minerals (Francolite) of Iran through the EDX-SEM to Assessment of Compositions in Nano-scale

In this work, the fine grains of Phosphate rocks forming minerals (francolite-Ca5(PO4,CO3)3F,OH) which belong to the geological formation of phosphate rocks of Zagros mountains in IRAN were detected, analyzed and interpreted by SEM-EDX in nano-scale. Moreover, the results are compared with the results of XRD analysis and straight observations of samples through the polarized microscope. Finding the composition of elements in minerals is the best path finder and also is very important in many geological investigations. The fine grain Phosphate minerals perform as traps which attract some kinds of elements. But sometimes these minerals are very fine and it is too difficult to determine and separate them for further studies. For instance, interpretation and investigation of the composition of fine minerals in Nano-scale by using single crystal X-ray Diffraction (Single-crystal XRD) analysis is impossible. Due to variety of minerals phases in a rock sample, the interpretations of the results of total elemental analysis, for example XRF, ICP, are not so real. Therefore, the best method for determination of elements in fine grain rock forming minerals is the study of minerals by the Scanning Electron Microscopy (SEM), with Energy Dispersive X-Ray Analysis (EDX).

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