{"title":"中等浓度聚合物溶液在横向剪切流中的流变性能的平均场理论","authors":"Walter Hess","doi":"10.1002/polc.5070730125","DOIUrl":null,"url":null,"abstract":"<p>Moderately concentrated polymer solutions are described as a suspension of interacting harmonic dumbbells. The interaction is treated in a mean field approximation. In the framework of this model the exact conformational distribution function for transversal shear flow is obtained. The shear viscosity and the first normal stress coefficient show the typical non-Newtonian form with a distinct power law behavior after the onset of shear rate dependence.</p>","PeriodicalId":16867,"journal":{"name":"Journal of Polymer Science: Polymer Symposia","volume":"73 1","pages":"201-215"},"PeriodicalIF":0.0000,"publicationDate":"1985-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1002/polc.5070730125","citationCount":"0","resultStr":"{\"title\":\"Mean field theory for the rheological properties of moderately concentrated polymer solutions in transversal shear flow\",\"authors\":\"Walter Hess\",\"doi\":\"10.1002/polc.5070730125\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Moderately concentrated polymer solutions are described as a suspension of interacting harmonic dumbbells. The interaction is treated in a mean field approximation. In the framework of this model the exact conformational distribution function for transversal shear flow is obtained. The shear viscosity and the first normal stress coefficient show the typical non-Newtonian form with a distinct power law behavior after the onset of shear rate dependence.</p>\",\"PeriodicalId\":16867,\"journal\":{\"name\":\"Journal of Polymer Science: Polymer Symposia\",\"volume\":\"73 1\",\"pages\":\"201-215\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1985-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1002/polc.5070730125\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Polymer Science: Polymer Symposia\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/polc.5070730125\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Polymer Science: Polymer Symposia","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/polc.5070730125","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Mean field theory for the rheological properties of moderately concentrated polymer solutions in transversal shear flow
Moderately concentrated polymer solutions are described as a suspension of interacting harmonic dumbbells. The interaction is treated in a mean field approximation. In the framework of this model the exact conformational distribution function for transversal shear flow is obtained. The shear viscosity and the first normal stress coefficient show the typical non-Newtonian form with a distinct power law behavior after the onset of shear rate dependence.
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