{"title":"溶剂在电子光谱中的位移。一系列同源芳香胺的斯托克斯移位","authors":"H.M. Rosenberg, E. Eimutis (2/Lt)","doi":"10.1016/0371-1951(66)80220-5","DOIUrl":null,"url":null,"abstract":"<div><p>The B<span>ilot</span> and K<span>awski</span> [1] equation, relating Stokes shift to solvent parameters, was applied to the electronic spectra of aromatic amines in various solvents. The equation was found to be in good agreement with the experimental data. In addition, the effect of hydrogen-bonding between solvent and solute was studied. The deviations of these systems from the theoretical equation provided an estimate of the energy of the specific interactions, which were found to be consistent with hydrogen-bond energy values. The theoretical significance of these results is discussed.</p></div>","PeriodicalId":101180,"journal":{"name":"Spectrochimica Acta","volume":"22 10","pages":"Pages 1751-1757"},"PeriodicalIF":0.0000,"publicationDate":"1966-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0371-1951(66)80220-5","citationCount":"17","resultStr":"{\"title\":\"Solvent shifts in electronic spectra—I. Stokes shift in a series of homologous aromatic amines\",\"authors\":\"H.M. Rosenberg, E. Eimutis (2/Lt)\",\"doi\":\"10.1016/0371-1951(66)80220-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The B<span>ilot</span> and K<span>awski</span> [1] equation, relating Stokes shift to solvent parameters, was applied to the electronic spectra of aromatic amines in various solvents. The equation was found to be in good agreement with the experimental data. In addition, the effect of hydrogen-bonding between solvent and solute was studied. The deviations of these systems from the theoretical equation provided an estimate of the energy of the specific interactions, which were found to be consistent with hydrogen-bond energy values. The theoretical significance of these results is discussed.</p></div>\",\"PeriodicalId\":101180,\"journal\":{\"name\":\"Spectrochimica Acta\",\"volume\":\"22 10\",\"pages\":\"Pages 1751-1757\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1966-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0371-1951(66)80220-5\",\"citationCount\":\"17\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Spectrochimica Acta\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0371195166802205\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Spectrochimica Acta","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0371195166802205","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Solvent shifts in electronic spectra—I. Stokes shift in a series of homologous aromatic amines
The Bilot and Kawski [1] equation, relating Stokes shift to solvent parameters, was applied to the electronic spectra of aromatic amines in various solvents. The equation was found to be in good agreement with the experimental data. In addition, the effect of hydrogen-bonding between solvent and solute was studied. The deviations of these systems from the theoretical equation provided an estimate of the energy of the specific interactions, which were found to be consistent with hydrogen-bond energy values. The theoretical significance of these results is discussed.
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