环境修复中可见光活性光催化剂的研究进展

K. Garadkar
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摘要

无金属有机聚合物和稳定的碳同素异形体,主要用于染料的降解。由于其低带隙(2.7 eV)和π-π,二维层状电子结构,它吸收可见光。g-C3N4和ZnO的耦合形成了一种新型支架纳米复合材料,这是一种提高光吸收率,更好的表面积和电荷载流子分离的有效方法。研究表明,Ag掺杂g- c3n4修饰的ZnO NPs (Ag-ZnO/gC 3n4 NCs)得到的复合材料具有较好的光催化剂性能。抗菌材料经常被使用,因为它们可以保护人类免受因细菌暴露或接触而引发的许多疾病。合成的NCs产生了相当大的抑制区,这表明它们具有良好的抗菌活性。活性氧破坏细胞膜,导致细胞死亡。采用一种简单、经济的共沉淀法合成了ZnO纳米粒子及其Ag和g- c3n4纳米复合材料。该方法收率高,材料纯度好,比其他方法有益,因为试剂在分子水平上混合,从而达到最佳的化学计量和形态,具有所需的材料尺寸。封盖剂SDS是阴离子表面活性剂,它能影响材料的形态和聚集,提高材料的光催化活性。封盖剂可以吸附在纳米颗粒表面,控制晶体平面的生长速度,从而限制纳米颗粒的大小和形状。提高氧化锌NPs的这些活性是研究的首要目标。研究成果对不同类型的环境修复具有一定的参考价值。光催化实验表明,1.0 mol%的Ag-ZnO NPs具有优异的光催化活性,在UV - Vis下对甲基橙(MO)的光降解能力比原始ZnO提高26%。这些结果表明,Ag掺入ZnO有助于提高O2•−和HO•活性自由基的形成速率
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Development of Visible Active Photocatalyst for the Environmental Remediation
, metal-free organic polymer and stable allotrope of carbon that is mostly employed for the degradation of dyes. It absorbs visible light due to its low band gap (2.7 eV) and π-π, 2D layered electronic structure. 4 The coupling of g-C3N4 and ZnO forms a novel scaffold nanocomposite which is a sensible way to improve light absorptivity, better surface area and charge carrier separation. The studies show that the modified ZnO NPs by Ag doping coupled with g-C 3 N 4 (Ag-ZnO/gC 3 N 4 NCs) produce a composite that shows improved properties of the photocatalyst. Antibacterial materials are frequently used because they can protect human beings from many diseases that are initiated due to bacterial exposure or contact. The synthesized NCs produced considerable zones of inhibition which point towardtheir good antibacterial activity. The reactive oxygen species damage the cellular membrane, leading to cell death.The ZnO NPs and their nanocomposites of Ag and g-C 3 N 4 are synthesized by a simple cost-effective co-precipitation method. This method provides a high yield with good purity of material and beneficial than other methods because the reagents are mixed at the molecular level so as to achieve the best stoichiometry and morphology with the desired size of thematerial. 5 The capping agent SDS is an anionic surfactant, it affects the morphology and aggregation ofmaterial which enhances the photocatalytic activity. The capping agent couldadsorb on nanoparticle surfaces and control the growth rate of crystallographic planes to limit the size and shape of nanoparticles. Boosting these activities of the ZnO NPs is the foremost goal of research. The research outcome will be helpful to different environmental remediation.The photocatalytic experiments showedthat the Ag-ZnO NPs (1.0 mol%) possessed excellent photocatalytic activity which exhibited a 26% increment in photodegradation of Methyl Orange (MO) compared to pristine ZnO under UV−Vis. the light within 90 min. These resultssuggest that Ag incorporated into ZnO will help to increase the rate offormation of O2•− and HO• reactive radicals,and
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