原始杂化钙钛矿CH3NH3PbI3的本征拉曼特征及其多阶段结构转变

Qiong Chen, Henan Liu, Hui‐Seon Kim, Yucheng Liu, Mengjin Yang, N. Yue, Gang Ren, K. Zhu, S. Liu, N. Park, Yong Zhang
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引用次数: 0

摘要

通过在不同光照条件下的空间分辨拉曼光谱和光致发光光谱,我们对三种不同技术合成的有机-无机杂化钙钛矿从原始状态(CH3NH3PbI3或MAPbI3)到完全降解状态(即PbI2)从介观尺度到宏观尺度的不同晶域尺寸样品的光谱特征有了统一的认识。
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Intrinsic Raman signatures of pristine hybrid perovskite CH3NH3PbI3 and its multiple stages of structure transformation
By performing spatially resolved Raman and photoluminescence spectroscopy with different illumination conditions, we have achieved a unified understanding towards the spectroscopy signatures of the organic-inorganic hybrid perovskite, transforming from the pristine state (CH3NH3PbI3 or MAPbI3) to fully degraded state (i.e., PbI2), for samples with varying crystalline domain size from mesoscopic scale to macroscopic size, synthesized by three different techniques.
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