从废棕榈叶中提取的二氧化硅灰作为环保、可持续的吸附剂用于铜的去除(II)。

IF 1.4 4区 环境科学与生态学 Q4 ENVIRONMENTAL SCIENCES Archives of Environmental Protection Pub Date : 2023-05-29 DOI:10.24425/aep.2023.145894
Fatima A. Al-Qadri, R. Alsaiari
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引用次数: 0

摘要

本研究描述了使用硅酸盐提取物作为前体的低成本二氧化硅材料的创造。这种前驱体是由廉价的棕榈叶废灰通过500°C的简单煅烧过程和用水的绿色萃取制成的。利用氮吸附-解吸、红外光谱分析和透射电镜对样品进行表征。所得介孔硅灰材料的比表面积为282 m2/g1,孔径为5.7 nm。对于铜离子的吸附,获得了一种优良的吸附剂。该廉价硅灰基吸附剂对重金属Cu(II)的最大吸附量为20 mg/g,考察了pH、温度和时间对其吸附量的影响。采用Langmuir和Freundlich模型拟合了吸附等温线,并采用拟一阶和拟二阶模型对吸附动力学进行了评价。结果表明,合成的吸附剂在pH为2 ~ 5的水溶液中均能有效去除重金属离子。吸附等温线遵循
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Silica ash from waste palm fronds used as an eco-friendly, sustainable adsorbent for the Removal of cupper (II).
: This study describes the creation of a low-cost silica material using a silicate extract as a precursor. This precursor is made from inexpensive palm frond waste ash through a simple calcination process at 500°C and a green extraction with water. Nitrogen adsorption-desorption, FTIR analyses, and transmission electron microscopy were used to characterize the samples. The surface area of the obtained mesoporous silica ash material was 282 m2/g1, and the pore size was 5.7 nm. For the adsorption of copper ions, an excellent adsorbent was obtained. The maximum copper ion adsorption capacity of this inexpensive silica ash-based adsorbent for removing heavy metal ions Cu(II) from aqueous solutions was 20 mg/g, and the eff ect of pH, temperature, and time on its adsorption capacity were also investigated. In addition, The adsorption isotherms were fi tted using Langmuir and Freundlich models, and the adsorption kinetics were evaluated using pseudo-fi rst-order and pseudo-second-order modelsThe results demonstrated that the synthesized adsorbent could eff ectively remove heavy metal ions from aqueous solutions at pH levels ranging from 2 to 5. The adsorption isotherms followed the
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来源期刊
Archives of Environmental Protection
Archives of Environmental Protection ENVIRONMENTAL SCIENCES-
CiteScore
2.70
自引率
26.70%
发文量
0
期刊介绍: Archives of Environmental Protection is the oldest Polish scientific journal of international scope that publishes articles on engineering and environmental protection. The quarterly has been published by the Institute of Environmental Engineering, Polish Academy of Sciences since 1975. The journal has served as a forum for the exchange of views and ideas among scientists. It has become part of scientific life in Poland and abroad. The quarterly publishes the results of research and scientific inquiries by best specialists hereby becoming an important pillar of science. The journal facilitates better understanding of environmental risks to humans and ecosystems and it also shows the methods for their analysis as well as trends in the search of effective solutions to minimize these risks.
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